This chapter covers basic concepts in power system operations and electricity markets. Basic concepts of power generation include variable cost, marginal cost, fixed cost, investment cost, the weighted average cost of capital, and the definition of a natural monopoly. Basic concepts of transmission and distribution include a discussion of Ohm’s law, Kirchhoff’s laws, the power flow equations, and the direct current power flow. Basic concepts of consumption include the notion of valuation/marginal benefit, demand functions, demand elasticity, and the value of lost load. The actors of electricity markets are introduced, including transmission/independent system operators, distribution system operators, utilities, load serving entities, retailers, power exchanges, and transmission companies. Reserves and ancillary services are then introduced, and details about the forward-looking and rolling nature of power system operations are discussed. Exchanges and pools are informally defined, and the debate between uniform and pay-as-bid pricing is detailed. A blueprint of a typical electricity markets, with the participating actors and traded products and services, is introduced. The California and Central Western European markets are compared in order to introduce the debate between zonal and nodal pricing, as well as different approaches in pricing.