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Inertial migration of an electrophoretic rigid sphere in a two-dimensional Poiseuille flow

Published online by Cambridge University Press:  12 July 2019

A. Choudhary
Affiliation:
Department of Chemical Engineering, Indian Institute of Technology, Chennai, TN 600036, India
T. Renganathan
Affiliation:
Department of Chemical Engineering, Indian Institute of Technology, Chennai, TN 600036, India
S. Pushpavanam*
Affiliation:
Department of Chemical Engineering, Indian Institute of Technology, Chennai, TN 600036, India
*
Email address for correspondence: spush@iitm.ac.in

Abstract

There has been a recent interest in integrating external fields with inertial microfluidic devices to tune particle focusing. In this work, we analyse the inertial migration of an electrophoretic particle in a two-dimensional Poiseuille flow with an electric field applied parallel to the walls. For a thin electrical double layer, the particle exhibits a slip-driven electrokinetic motion along the direction of the applied electric field, which causes the particle to lead or lag the flow (depending on its surface charge). The fluid disturbance caused by this slip-driven motion is characterized by a rapidly decaying source-dipole field which alters the inertial lift on the particle. We determine this inertial lift using the reciprocal theorem. Assuming no wall effects, we derive an analytical expression for a ‘phoretic lift’ which captures the modification to the inertial lift due to electrophoresis. We also take wall effects into account, at the leading order, using the method of reflections. We find that for a leading particle, the phoretic lift acts towards the regions of high shear (i.e. walls), while the reverse is true for a lagging particle. Using an order-of-magnitude analysis, we obtain different components of the inertial force and classify them on the basis of the interactions from which they emerge. We show that the dominant contribution to the phoretic lift originates from the interaction of the source-dipole field (generated by the electrokinetic slip at the particle surface) with the stresslet field (generated due to particle’s resistance to strain in the background flow). Furthermore, to contrast the slip-driven phenomenon (electrophoresis) from the force-driven phenomenon (buoyancy) in terms of their influence on the inertial migration, we also study a non-neutrally buoyant particle. We show that the gravitational effects alter the inertial lift primarily through the interaction of the background shear with the buoyancy-induced Stokeslet field.

Type
JFM Papers
Copyright
© 2019 Cambridge University Press 

1 Introduction

1.1 Inertial migration

Inertial focusing is the cross-stream migration of particles in the presence of finite fluid inertia. This phenomenon was first observed by Segre & Silberberg (Reference Segre and Silberberg1961, Reference Segre and Silberberg1962a ,Reference Segre and Silberberg b ). Their experiments revealed a cross-stream migration of a dilute suspension of rigid neutrally buoyant particles in a pressure-driven flow. The peak concentration of the particles occurred at a radial position of ${\sim}0.6\,R_{p}$ , where $R_{p}$ is the pipe radius. Bretherton (Reference Bretherton1962) showed that in the absence of inertia (i.e. Stokes regime), a rigid sphere cannot migrate across streamlines owing to the reversibility of the Stokes flow. Therefore, cross-stream migration was attributed to the fluid inertia.

To qualitatively understand this behaviour, the first theoretical studies were conducted for unbounded flows. Rubinow & Keller (Reference Rubinow and Keller1961) used matched asymptotic expansion to find the inertial force on a particle exhibiting constant rotation in a uniform flow. They found a viscosity independent force in a direction perpendicular to the axis of rotation and the incident flow. In a Poiseuille flow, this force always acts towards the axis of the channel which contradicts the observations of Segre & Silberberg (Reference Segre and Silberberg1961). Therefore their results failed to explain the primary reason behind the lateral migration. Later Saffman (Reference Saffman1965) derived an expression for the lift on a small sphere exhibiting a relative motion along the streamlines of an unbounded shear flow. Saffman demonstrated that a particle would migrate towards the regions of higher relative velocity; a particle leading (or lagging) in a shear flow would migrate transversely towards the region of low (or high) velocity. Although this study aided in understanding some aspects of the migration observed by Segre-Silberberg (buoyancy and near-wall effects), it could not explain the migration of neutrally buoyant particles.

Migration of a particle in the presence of boundaries was first studied in great generality by Cox & Brenner (Reference Cox and Brenner1968). They considered a spherical particle suspended in a three-dimensional Poiseuille flow. They made a crucial observation that, in bounded flows, the viscous stresses are more dominant than the inertial stresses, provided $Re_{V}\ll \unicode[STIX]{x1D705}$ ( $Re_{V}$ is the particle Reynolds number defined as: $V^{\prime }a^{\prime }/\unicode[STIX]{x1D708}^{\prime }$ , where $V^{\prime }$ is the particle velocity relative to the background flow, $\unicode[STIX]{x1D708}^{\prime }$ is the kinematic viscosity and $\unicode[STIX]{x1D705}$ is the ratio of particle radius $a^{\prime }$ to the channel height $l^{\prime }$ ). Using a regular perturbation expansion, they derived an expression for migration velocity as a volume integral involving the velocity field in Stokes regime (these velocity fields were represented in terms of Green’s function). However, the solution was not provided in an explicit form as it involved numerous integrals. Therefore no conclusions were drawn with respect to lateral migration or equilibrium positions.

Ho & Leal (Reference Ho and Leal1974) studied the migration of a neutrally buoyant particle in a two-dimensional (2-D) Couette and Poiseuille flow and were the first to calculate the lift force explicitly. Similar to Cox & Brenner (Reference Cox and Brenner1968) they found that the viscous stresses dominate throughout the channel, provided $Re_{p}\ll \unicode[STIX]{x1D705}^{2}$ . Here $Re_{p}=U_{max}^{\prime }\unicode[STIX]{x1D705}a^{\prime }/\unicode[STIX]{x1D708}^{\prime }$ is the particle Reynolds number based on the average shear rate ( $U_{max}^{\prime }$ is the maximum centreline velocity). They employed a regular perturbation expansion in $Re_{p}$ in conjunction with Lorentz reciprocal theorem to find the inertial lift as a volume integral over creeping flow velocities. These velocities were found using the method of reflections and wall corrections were incorporated using Faxén transformations (originally developed by Faxén (Reference Faxén1922) for bounded viscous flows). For Poiseuille flow, the equilibrium positions were found to be in agreement with the observations of Segre & Silberberg (Reference Segre and Silberberg1961) i.e. ${\sim}0.6$ times the half-channel width. Recently, Hood, Lee & Roper (Reference Hood, Lee and Roper2015) extended the approach of Ho & Leal (Reference Ho and Leal1974) to a 3-D Poiseuille flow. They derived an asymptotic model and calculated lift on the particle as a function of size ratio $\unicode[STIX]{x1D705}$ . Through a numerical analysis, they demonstrated that the methodology developed by Ho and Leal was applicable over a wider range of $Re_{p}$ than their theoretical constraint, $Re_{p}\ll \unicode[STIX]{x1D705}^{2}$ .

Vasseur & Cox (Reference Vasseur and Cox1976) used the general results of Cox & Brenner (Reference Cox and Brenner1968) to compute the inertial lift on neutrally and non-neutrally buoyant spherical particles in 2-D Couette and Poiseuille flows. They approximated the particle as a point force and used an approach based on Green’s functions to solve for the flow field. Their results for the migration velocity of neutrally buoyant particles showed a significant deviation from that obtained by Ho & Leal (Reference Ho and Leal1974) near the walls.

1.2 Electrophoresis tuned inertial focusing

In the past decade, numerous experimental studies have focused on the implementation of inertial focusing in microfluidic Lab-on-Chip devices to separate and trap, particles and cells (Martel & Toner Reference Martel and Toner2014; Zhang et al. Reference Zhang, Yan, Yuan, Alici, Nguyen, Warkiani and Li2016). There has been a recent interest towards the integration of external electric fields with inertial microfluidics to have an active control over particle migration. This can be exploited to separate particles and biological cells on the basis of their ability to acquire a surface charge when suspended in an aqueous (polar) medium. Recent experimental studies by Kim & Yoo (Reference Kim and Yoo2009a ,Reference Kim and Yoo b ), Cevheri & Yoda (Reference Cevheri and Yoda2014), Yuan et al. (Reference Yuan, Pan, Zhang, Yan, Zhao, Alici and Li2016), Li & Xuan (Reference Li and Xuan2018) and Rossi et al. (Reference Rossi, Marin, Cevheri, Kähler and Yoda2019) demonstrated an electric field-induced lateral migration by making a polystyrene microsphere lag behind the background Poiseuille flow (this – electric field imposed – relative motion is in addition to the lag induced by the curvature of the background Poiseuille flow and interaction with the boundaries). The particles were observed to focus on the axis (or walls) of the channel when they were made to lag (or lead) the pressure driven flow.

A common hypothesis put forth by these experimental studies is that a charged particle under the action of a parallel Coulombic force leads or lags the background flow analogous to a non-neutrally buoyant particle suspended in a Poiseuille flow (with gravity aligned parallel to the flow) which generates a Saffman lift (Saffman Reference Saffman1965). However, a closer examination reveals differences in the two phenomena. The mechanism by which the lag/lead occurs due to gravitational field is fundamentally different from that in an electrolytic medium due to the external electric field. In the latter, a layer of ions (consisting primarily of the counter-ions) forms around the charged particle by electrostatic attraction. This layer is subject to a thermo-electrostatic equilibrium and is known as the electrical double layer. The particles used in the experiments (Li & Xuan Reference Li and Xuan2018) were a few micrometres in diameter, with a zeta potential a few times the thermal potential ( ${\sim}25~\text{mV}$ ). The double layer ( $\unicode[STIX]{x1D706}_{d}^{\prime }$ ) associated with such particles is a few nanometres thick. Therefore, these systems lie in the thin-double-layer limit ( $\unicode[STIX]{x1D706}_{d}^{\prime }/a^{\prime }\ll 1$ ). In such cases, an external field does not affect the particle directly as a thin ionic layer shields it. The external field however, exerts a Coulomb force on the fluid in the thin layer (as the net charge is non-zero), resulting in a tangential slip on the surface of the particle. As a result, a freely suspended particle moves in the direction opposite to the slip, known as electrophoresis (Kirby Reference Kirby2010).

Figure 1. Disturbance velocity fields around the particle in a quiescent fluid for movements due to (a) forced (sedimentation) and (b) force-free (phoresis) mechanisms. The external field is applied in the horizontal direction.

In the absence of boundaries, electrophoretic motion corresponding to such particles can be viewed as ‘force-free’ and is fundamentally different from the motion associated with sedimentation (Anderson Reference Anderson1989). Figure 1 shows the disturbance a particle creates in a quiescent fluid when subjected to these two mechanisms. The force-free phoretic particle motion occurs due to slipping of counter-ions over its surface. The associated disturbance field is governed by a rapidly decaying source-dipole field ( ${\sim}O(1/r^{3})$ ). However, the disturbance field generated from the motion induced due to density difference (buoyancy-induced motion), on the contrary, is a Stokeslet at the leading order (flow field generated due to point force), which decays significantly slower ( ${\sim}O(1/r)$ ). This Stokeslet upon interaction with the background shear gives rise to a buoyancy combined inertial migration (Feng, Hu & Joseph Reference Feng, Hu and Joseph1994; Matas, Morris & Guazzelli Reference Matas, Morris and Guazzelli2004). Since a direct analogy cannot be extended, the question then arises as to how electrophoresis affects inertial migration and what are the responsible underlying interactions?

Apart from the inertial lift, there are various other forces which act laterally on an electrophoretic particle. Yariv (Reference Yariv2006) found that a wall-repulsive electric force acts on the electrophoretic particle when a parallel electric field is applied. As this force arises from the asymmetry in Maxwell stresses, it is decoupled from the hydrodynamics and gets altered in the presence of surface conduction effects (Yariv Reference Yariv2016). In addition to this, an externally imposed mechanical flow over an electrophoretic particle generates a ‘streaming potential’ (which arises due to streaming of ions inside the double layer). Schnitzer, Frankel & Yariv (Reference Schnitzer, Frankel and Yariv2012a ) showed that this consequently generates a streaming electric field which is $O(\unicode[STIX]{x1D706}_{d}^{\prime }/a^{\prime })^{2}$ for moderate Péclet numbers: $Pe\sim O(1)$ ( $Pe=\unicode[STIX]{x1D705}U_{max}^{\prime }a^{\prime }/D_{i}^{\prime }$ , where $D_{i}^{\prime }$ is the ionic diffusivity). Since we consider the double layer to be asymptotically thin ( $\unicode[STIX]{x1D706}_{d}^{\prime }/a^{\prime }\ll 1$ ), the effect of streaming potential is neglected in this work. However, in the aforementioned regime, the streaming potential may generate when the particle is very near the walls. This modifies the electrokinetic slip, and the associated Newtonian stresses result in a lateral ‘electro-viscous force’ (Bike & Prieve Reference Bike and Prieve1995; Schnitzer & Yariv Reference Schnitzer and Yariv2016). In this work, we neglect the electro-viscous force and focus on the migration in the bulk of the channel. For the same reason, we exclude the forces arising from (i) the van der Waals interactions and (ii) interactions of the double layer between particle and walls.

Table 1. A summary of theoretical studies in the past addressing various forces acting on the particle. The table is divided with respect to origin of the lift: (i) weak inertia and (ii) electrostatics and electrokinetics. $Re$ is the flow Reynolds number; $Re_{p}$ is the particle Reynolds number based on average shear; $Re_{V}$ is the particle Reynolds number based on particle velocity relative to background flow; $Pe$ is the Péclet number defined as $a^{\prime 2}G^{\prime }/D_{i}^{\prime }$ ( $G^{\prime }$ is the background velocity gradient and $D_{i}^{\prime }$ being the ionic diffusion coefficient of $i$ th ionic species); $\unicode[STIX]{x1D716}$ is the particle–wall gap, non-dimensionalized with respect to particle radius $a^{\prime }$ .

Table 1 summarizes various theoretical studies in the past which analysed lateral migration of neutral and electrophoretic particles in different regimes. Recent experimental studies (Kim & Yoo Reference Kim and Yoo2009a ,Reference Kim and Yoo b ; Cevheri & Yoda Reference Cevheri and Yoda2014; Yuan et al. Reference Yuan, Pan, Zhang, Yan, Zhao, Alici and Li2016; Li & Xuan Reference Li and Xuan2018; Rossi et al. Reference Rossi, Marin, Cevheri, Kähler and Yoda2019) discuss the electric field effect on the migration of electrophoretic particles in Poiseuille flow. However, the physical cause and magnitude of this effect remains unclear. Also, a closer look at table 1 sparks a further question: Does a slip-driven motion (electrophoresis) have a different effect on inertial migration than a force-driven motion (movement due to buoyancy)?

Motivated by the recent experimental studies, the objectives of this work are: (i) to study the inertial lift on an electrophoretic sphere in a combined electro-osmotic Poiseuille flow, (ii) to obtain physical insight on the various interactions which contribute to the migration of an electrophoretic particle, (iii) and to draw comparisons with the buoyancy combined inertial lift. The parameters reported by the experimental studies (Kim & Yoo Reference Kim and Yoo2009a ,Reference Kim and Yoo b ; Cevheri & Yoda Reference Cevheri and Yoda2014; Yuan et al. Reference Yuan, Pan, Zhang, Yan, Zhao, Alici and Li2016; Li & Xuan Reference Li and Xuan2018; Yee & Yoda Reference Yee and Yoda2018; Rossi et al. Reference Rossi, Marin, Cevheri, Kähler and Yoda2019) correspond to the regime of weak inertia, where the entire domain is dominated by viscous forces. Therefore, our approach builds on the framework of Ho & Leal (Reference Ho and Leal1974).

This work is organized as follows: the problem formulation and different simplifying assumptions are presented in § 2. We apply a regular perturbation expansion in $Re_{p}$ , and derive the lift force using the Lorentz reciprocal theorem. In § 3, the electrostatic potential and velocity fields are found using the method of reflections. We employ Lamb’s general solution (Lamb Reference Lamb1975) and Faxén’s transform (Faxén Reference Faxén1922) to calculate the reflections of fields. In § 4, we draw qualitative insights into the migration behaviour by neglecting wall effects and derive an approximate expression for a ‘phoretic lift’. In § 5, we summarize the solution methodology. We illustrate the migration of an inert particle and validate our results with the previous studies in § 6. In § 7, the effect of electrophoresis on the inertial lift is analysed. The different constituents contributing to the lift force are analysed here. In § 8, we study a non-neutrally buoyant particle and draw comparisons with the electrophoretic particle in terms of their influence on the inertial migration. In § 9, we discuss a decoupled electrical lift force which stems from the Maxwell stresses (Yariv Reference Yariv2006) and compare it with the inertial lift. The key results and conclusions are discussed in § 10. Appendices and supplementary material available at https://doi.org/10.1017/jfm.2019.479 provide the details of calculations for the interested reader.

2 Problem formulation

The system analysed in this work is shown in figure 2. It depicts a neutrally buoyant particle of radius $a^{\prime }$ suspended in a combined electro-osmotic Poiseuille flow of an electrolytic solution, moving with a maximum velocity of $U_{max}^{\prime }$ (where $^{\prime }$ denotes dimensional variables). The system is subjected to an externally imposed uniform electric field parallel to the walls ( $\boldsymbol{E}_{\infty }^{\prime }=E_{\infty }^{\prime }\boldsymbol{e}_{x}$ ). Both the particle and wall surface are assumed to have a constant zeta potential. The origin of Cartesian coordinate system is placed at the particle centre, which is located at a distance $d^{\prime }$ from the bottom wall. The thin double layer is depicted by dashed lines in figure 2. We analyse the system under the thin-double-layer limit ( $\unicode[STIX]{x1D706}_{d}^{\prime }/a^{\prime }\ll 1$ ). The thin-double-layer assumption implies that the ionic distribution in it is at quasi-equilibrium. Here $\unicode[STIX]{x1D706}_{d}^{\prime }$ denotes the thickness of the electrical double layer. At large zeta potentials, the conduction of ions in the double layer can exceed than that in the bulk. As a result, polarization of ions occurs inside the double layer, formally known as the surface conduction effect (O’Brien & White Reference O’Brien and White1978; O’Brien & Hunter Reference O’Brien and Hunter1981). In this work, since we do not address logarithmically large zeta potentials (Schnitzer & Yariv Reference Schnitzer and Yariv2012), we neglect the surface conduction effects.

Figure 2. Schematic depicting the problem configuration and the coordinate system in particle reference frame. The dashed layer around the particle and walls depicts the outer edge of the double layer. Prime denotes the dimensional variables and $\unicode[STIX]{x1D703}$ denotes the polar angle measured from the $z^{\prime }$ -axis;  $a^{\prime }$ includes the particle radius and thin electrical double layer $\unicode[STIX]{x1D706}_{d}^{\prime }$ .

2.1 Governing equations

We represent the system in non-dimensional variables using $a^{\prime }$ , $\unicode[STIX]{x1D705}U_{max}^{\prime }$ , $\unicode[STIX]{x1D707}^{\prime }\unicode[STIX]{x1D705}U_{max}^{\prime }/a^{\prime }$ and $a^{\prime }|E_{\infty }^{\prime }|$ as the characteristic scales for length, velocity, pressure and electrostatic potential, respectively. Here, $\unicode[STIX]{x1D705}$ is the size ratio of the particle radius $a^{\prime }$ to the channel width $l^{\prime }$ , and $\unicode[STIX]{x1D707}^{\prime }$ denotes the viscosity of the electrolyte. If no external concentration gradient is applied, the electrostatic potential ( $\unicode[STIX]{x1D719}$ ) in the ‘electro-neutral’ bulk region (zero charge density) is governed by the Laplace equation

(2.1) $$\begin{eqnarray}\unicode[STIX]{x1D6FB}^{2}\unicode[STIX]{x1D719}=0.\end{eqnarray}$$

Since the effect of streaming potential is neglected in this work, a no-flux condition for the electrostatic potential is imposed at the surface of the particle

(2.2) $$\begin{eqnarray}\boldsymbol{e}_{r}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}=0\quad \text{at }r=1.\end{eqnarray}$$

The electric field remains parallel to the walls (located at $z=s$ and $z=1-s$ , where $s\equiv d^{\prime }/l^{\prime }$ ), yielding

(2.3) $$\begin{eqnarray}\boldsymbol{e}_{z}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}=0\quad \text{at walls}.\end{eqnarray}$$

Far away from the particle, the electric potential distribution approaches its undisturbed state ( $\unicode[STIX]{x1D719}_{\infty }\sim -x$ )

(2.4) $$\begin{eqnarray}\unicode[STIX]{x1D719}\rightarrow \unicode[STIX]{x1D719}_{\infty }\quad \text{as }r\rightarrow \infty .\end{eqnarray}$$

The hydrodynamics of the current problem consists of three time scales: (i) viscous time scale ( $t_{visc}^{\prime }\sim a^{\prime 2}/\unicode[STIX]{x1D708}^{\prime }$ ), (ii) convective time scale of the flow ( $t_{conv}^{\prime }\sim a^{\prime }/\unicode[STIX]{x1D705}U_{max}^{\prime }$ ) and (iii) migration (or geometric) time scale ( $t_{mig}^{\prime }\sim a^{\prime }/U_{mig}^{\prime }$ ). Since the time dependence enters the system through the migration time scale, temporal variations can be assumed to be negligible if the migration time scale is much larger than the convective time scale ( $t_{mig}^{\prime }\gg t_{conv}^{\prime }$ ) (Becker, McKinley & Stone Reference Becker, McKinley and Stone1996). Since the migration occurs due to weak inertia, the migration velocity is much smaller than the characteristic velocity ( $U_{mig}^{\prime }\ll \unicode[STIX]{x1D705}U_{max}^{\prime }$ ), which suggests that we can neglect the temporal variations. Therefore, the velocity and pressure distribution in the electroneutral bulk are governed by continuity and quasi-steady Navier–Stokes equation. The term quasi-steady implies that the dynamics depends only on the instantaneous geometric configuration (i.e. particle position between the walls), provided $U_{mig}^{\prime }\ll \unicode[STIX]{x1D705}U_{max}^{\prime }$ . (A detailed derivation is described in the supplementary material S1.) In the frame of reference of the moving particle, the flow is governed by

(2.5a,b ) $$\begin{eqnarray}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{U}=0,\quad \unicode[STIX]{x1D6FB}^{2}\boldsymbol{U}-\unicode[STIX]{x1D735}P=\mathit{Re}_{p}(\boldsymbol{U}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{U}).\end{eqnarray}$$

Here, $Re_{p}$ is particle Reynolds number defined as

(2.6) $$\begin{eqnarray}\mathit{Re}_{p}=\frac{\unicode[STIX]{x1D70C}^{\prime }U_{max}^{\prime }\unicode[STIX]{x1D705}a^{\prime }}{\unicode[STIX]{x1D707}^{\prime }}.\end{eqnarray}$$

The sphere moves with a – yet to be determined – translational and rotational velocity: $\boldsymbol{U}_{s}$ and $\unicode[STIX]{x1D734}_{s}$ , respectively. Since the domain is infinite in the $y$ -direction, we can consider: $\boldsymbol{U}_{s}=U_{sx}\boldsymbol{e}_{x}+U_{sz}\boldsymbol{e}_{z}$ and $\unicode[STIX]{x1D734}_{s}=\unicode[STIX]{x1D6FA}_{sy}\boldsymbol{e}_{y}$ (i.e. the particle rotates in the direction of the background flow vorticity). To account for the electrokinetic effects inside the double layer, we employ a macroscale description i.e. the slip-boundary condition derived by Smoluchowski (Reference Smoluchowski1903). We obtain the following boundary condition at the particle surface:

(2.7) $$\begin{eqnarray}\boldsymbol{U}=\unicode[STIX]{x1D734}_{s}\times \boldsymbol{r}+HaZ_{p}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}\quad \text{at }r=1.\end{eqnarray}$$

Here, $Z_{p}$ is the dimensionless particle surface zeta potential ( $\unicode[STIX]{x1D701}_{p}^{\prime }/|E_{\infty }^{\prime }|a^{\prime }$ ). $Ha$ is a Hartmann-type number: $Ha=\unicode[STIX]{x1D700}^{\prime }E_{\infty }^{\prime 2}a^{\prime }/4\unicode[STIX]{x03C0}\unicode[STIX]{x1D707}^{\prime }\unicode[STIX]{x1D705}U_{max}^{\prime }$ , which denotes the ratio of electrical energy density to shear stress. Here $\unicode[STIX]{x1D700}^{\prime }$ is the electrical permittivity. In this work, based on the experimental conditions (Kim & Yoo Reference Kim and Yoo2009a ; Cevheri & Yoda Reference Cevheri and Yoda2014; Li & Xuan Reference Li and Xuan2018), we address the $Ha\sim O(1)$ and $Z_{p}\sim O(1)$ regime ( $E_{\infty }^{\prime }\approx O(10^{3}){-}O(10^{4})~\text{V}~\text{m}^{-1}$ , $\unicode[STIX]{x1D701}_{p}^{\prime }=50~\text{mV}$ , $a^{\prime }=10~\unicode[STIX]{x03BC}\text{m}$ , $\unicode[STIX]{x1D707}=10^{-3}~\text{Pa}~\text{s}$ , $U_{max}^{\prime }=2.25~\text{mm}~\text{s}^{-1}$ , $\unicode[STIX]{x1D705}=10^{-2}$ , $\unicode[STIX]{x1D700}^{\prime }=80\unicode[STIX]{x1D700}_{vacuum}^{\prime }$ ).

At walls ( $z=s$ and $z=1-s$ ), the flow satisfies the Smoluchowski slip condition

(2.8) $$\begin{eqnarray}\boldsymbol{U}=HaZ_{w}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}-\boldsymbol{U}_{s}\quad \text{at walls.}\end{eqnarray}$$

Here, $Z_{w}$ is the dimensionless wall surface zeta potential ( $\unicode[STIX]{x1D701}_{w}^{\prime }/|E_{\infty }^{\prime }|a^{\prime }$ ). The flow remains undisturbed far away from the particle and satisfies

(2.9) $$\begin{eqnarray}\boldsymbol{U}\rightarrow \boldsymbol{V}_{\infty }\quad \text{as }r\rightarrow \infty .\end{eqnarray}$$

Here, $\boldsymbol{V}_{\infty }$ denotes the undisturbed background flow (Poiseuille flow combined with electro-osmosis) in the frame of reference of the particle

(2.10) $$\begin{eqnarray}\boldsymbol{V}_{\infty }=(\unicode[STIX]{x1D6FC}+\unicode[STIX]{x1D6FD}z+\unicode[STIX]{x1D6FE}z^{2})\boldsymbol{e}_{x}+HaZ_{w}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{\infty }-\boldsymbol{U}_{s}.\end{eqnarray}$$

The constants $\unicode[STIX]{x1D6FC}$ , $\unicode[STIX]{x1D6FD}$ and $\unicode[STIX]{x1D6FE}$ are

(2.11a-c ) $$\begin{eqnarray}\unicode[STIX]{x1D6FC}=4U_{max}s(1-s),\quad \unicode[STIX]{x1D6FD}=4U_{max}\unicode[STIX]{x1D705}(1-2s),\quad \unicode[STIX]{x1D6FE}=-4U_{max}\unicode[STIX]{x1D705}^{2},\end{eqnarray}$$

where $\unicode[STIX]{x1D6FD}$ and $\unicode[STIX]{x1D6FE}$ represent the shear and curvature of the background flow.

Determination of $\boldsymbol{U}_{s}$ and $\unicode[STIX]{x1D734}_{s}$ . The translational and rotational velocities of the sphere are evaluated by acknowledging that the freely suspended neutral particle (charged surface plus counter-ions) is force-free and torque-free (see § A.1 for details). Therefore, in the formulation above, the overall (hydrodynamic and electric) force ( $\boldsymbol{F}_{H}+\boldsymbol{F}_{M}$ ) and torque ( $\boldsymbol{L}_{H}+\boldsymbol{L}_{M}$ ) on the particle must be zero,

(2.12) $$\begin{eqnarray}\displaystyle & \displaystyle \boldsymbol{F}=\boldsymbol{F}_{H}+\boldsymbol{F}_{M}=\int _{S_{p}}\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D72E}_{H}\,\text{d}S+4\unicode[STIX]{x03C0}Ha\int _{S_{p}}\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D72E}_{M}\,\text{d}S=\mathbf{0}, & \displaystyle\end{eqnarray}$$
(2.13) $$\begin{eqnarray}\displaystyle & \displaystyle \boldsymbol{L}=\boldsymbol{L}_{H}+\boldsymbol{L}_{M}=\int _{S_{p}}\boldsymbol{n}\times (\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D72E}_{H})\,\text{d}S+4\unicode[STIX]{x03C0}Ha\int _{S_{p}}\boldsymbol{n}\times (\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D72E}_{M})\,\text{d}S=\mathbf{0}. & \displaystyle\end{eqnarray}$$

The above force and torque have been normalized with $\unicode[STIX]{x1D707}^{\prime }a^{\prime }\unicode[STIX]{x1D705}U_{max}^{\prime }$ and $\unicode[STIX]{x1D707}^{\prime }a^{\prime 2}\unicode[STIX]{x1D705}U_{max}^{\prime }$ , respectively. Here, $\unicode[STIX]{x1D72E}_{H}$ is the dimensionless Newtonian stress tensor which contributes to hydrodynamic force; $\unicode[STIX]{x1D72E}_{M}$ is the dimensionless Maxwell stress tensor which contributes to the electric force

(2.14a,b ) $$\begin{eqnarray}\unicode[STIX]{x1D72E}_{H}=-P\unicode[STIX]{x1D644}+\unicode[STIX]{x1D735}\boldsymbol{U}+(\unicode[STIX]{x1D735}\boldsymbol{U})^{\text{T}}\quad \text{and}\quad \unicode[STIX]{x1D72E}_{M}=\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}-{\textstyle \frac{1}{2}}(\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\unicode[STIX]{x1D719})\unicode[STIX]{x1D644}.\end{eqnarray}$$

Here, $\unicode[STIX]{x1D644}$ is the second-order identity tensor and the superscript T denotes transpose.

2.2 Equations governing the disturbance

The solution to (2.1)–(2.5), (2.7)–(2.9), (2.12) and (2.13) is sought in terms of disturbance variables: electrostatic potential ( $\unicode[STIX]{x1D713}=\unicode[STIX]{x1D719}-\unicode[STIX]{x1D719}_{\infty }$ ), velocity ( $\boldsymbol{v}=\boldsymbol{U}-\boldsymbol{V}_{\infty }$ ) and pressure ( $p=P-P_{\infty }$ ). These represent the deviation of actual fields from the undisturbed fields. The disturbance electrostatic potential is governed by

(2.15) $$\begin{eqnarray}\unicode[STIX]{x1D6FB}^{2}\unicode[STIX]{x1D713}=0,\end{eqnarray}$$

and is subject to the following boundary conditions:

(2.16) $$\begin{eqnarray}\displaystyle & \boldsymbol{e}_{r}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}=-\boldsymbol{e}_{r}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{\infty }\quad \text{at }r=1, & \displaystyle\end{eqnarray}$$
(2.17) $$\begin{eqnarray}\displaystyle & \boldsymbol{e}_{z}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}=0\quad \text{at walls}, & \displaystyle\end{eqnarray}$$
(2.18) $$\begin{eqnarray}\displaystyle & \unicode[STIX]{x1D713}\rightarrow 0\quad \text{as }r\rightarrow \infty . & \displaystyle\end{eqnarray}$$

The disturbance velocity is governed by

(2.19a,b ) $$\begin{eqnarray}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{v}=0,\quad \unicode[STIX]{x1D6FB}^{2}\boldsymbol{v}-\unicode[STIX]{x1D735}p=Re_{p}(\boldsymbol{v}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}+\boldsymbol{v}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{V}_{\infty }+\boldsymbol{V}_{\infty }\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}),\end{eqnarray}$$

and is subject to the following boundary conditions:

(2.20) $$\begin{eqnarray}\displaystyle & \boldsymbol{v}=\unicode[STIX]{x1D734}_{s}\times \boldsymbol{r}+HaZ_{p}\unicode[STIX]{x1D735}(\unicode[STIX]{x1D713}+\unicode[STIX]{x1D719}_{\infty })-\boldsymbol{V}_{\infty }\quad \text{at }r=1, & \displaystyle\end{eqnarray}$$
(2.21) $$\begin{eqnarray}\displaystyle & \boldsymbol{v}=HaZ_{w}\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}\quad \text{at walls,} & \displaystyle\end{eqnarray}$$
(2.22) $$\begin{eqnarray}\displaystyle & \boldsymbol{v}\rightarrow \mathbf{0}\quad \text{as }r\rightarrow \infty . & \displaystyle\end{eqnarray}$$

The disturbance hydrodynamic and Maxwell stresses are defined as

(2.23a,b ) $$\begin{eqnarray}\unicode[STIX]{x1D748}_{H}=-p\unicode[STIX]{x1D644}+\unicode[STIX]{x1D735}\boldsymbol{v}+(\unicode[STIX]{x1D735}\boldsymbol{v})^{\text{T}}\quad \unicode[STIX]{x1D748}_{M}=\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}-{\textstyle \frac{1}{2}}(\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\unicode[STIX]{x1D713})\unicode[STIX]{x1D644}.\end{eqnarray}$$

Since only the disturbance stresses must contribute to force and torque on the particle, we write

(2.24) $$\begin{eqnarray}\displaystyle & \displaystyle \boldsymbol{F}=\boldsymbol{F}_{H}+\boldsymbol{F}_{M}=\int _{S_{p}}\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{H}\,\text{d}S+4\unicode[STIX]{x03C0}Ha\int _{S_{p}}\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{M}\,\text{d}S=\mathbf{0}, & \displaystyle\end{eqnarray}$$
(2.25) $$\begin{eqnarray}\displaystyle & \displaystyle \boldsymbol{L}=\boldsymbol{L}_{H}+\boldsymbol{L}_{M}=\int _{S_{p}}\boldsymbol{n}\times (\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{H})\,\text{d}S+4\unicode[STIX]{x03C0}Ha\int _{S_{p}}\boldsymbol{n}\times (\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{M})\,\text{d}S=\mathbf{0}. & \displaystyle\end{eqnarray}$$

2.3 Regular perturbation expansion

The primary objective of this work is to obtain the lift associated with inertia for an asymptotically small $Re_{p}$ . Towards this, we perform a regular perturbation expansion in $Re_{p}$ . This expansion is valid only when the inertia persists as a perturbation throughout the domain. Therefore, the wall particle distance must be shorter than the length scale where the inertial force balances viscous force (Guazzelli & Morris Reference Guazzelli and Morris2011). The order of magnitude of the ratio of inertial to viscous forces shows that the length scale associated with the bulk shear ( $a^{\prime }/\sqrt{Re_{p}}$ ) is much shorter than that based on the electrokinetic slip ( $a^{\prime }/HaZ_{p}Re_{p}$ ). Therefore, based on the inertial length scale of bulk shear, we arrive at the following constraint for the entire domain to be dominated by viscous forces

(2.26) $$\begin{eqnarray}O(Re_{p})\ll \unicode[STIX]{x1D705}^{2}.\end{eqnarray}$$

This allows us to seek the solution for disturbance velocity, pressure, translational and rotational velocities as a perturbation expansion in $Re_{p}$

(2.27) $$\begin{eqnarray}\left.\begin{array}{@{}c@{}}\boldsymbol{v}=\boldsymbol{v}^{(0)}+Re_{p}\boldsymbol{v}^{(1)}+\cdots \quad p=p^{(0)}+Re_{p}p^{(1)}+\cdots \,,\\ \boldsymbol{U}_{s}=\boldsymbol{U}_{s}^{(0)}+Re_{p}\boldsymbol{U}_{s}^{(1)}+\cdots \quad \unicode[STIX]{x1D734}_{s}=\unicode[STIX]{x1D734}_{s}^{(0)}+Re_{p}\unicode[STIX]{x1D734}_{s}^{(1)}+\cdots \,.\end{array}\right\}\end{eqnarray}$$

We substitute the above expansion into the equations governing hydrodynamics (2.19)–(2.22). We obtain the $O(1)$ problem as

(2.28) $$\begin{eqnarray}\left.\begin{array}{@{}rcl@{}}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{v}^{(0)}\, & =\, & 0,\\ \unicode[STIX]{x1D6FB}^{2}\boldsymbol{v}^{(0)}-\unicode[STIX]{x1D735}p^{(0)}\, & =\, & \mathbf{0},\\ \boldsymbol{v}^{(0)}\, & =\, & \unicode[STIX]{x1D734}_{s}^{(0)}\times \boldsymbol{r}+HaZ_{p}\unicode[STIX]{x1D735}(\unicode[STIX]{x1D713}+\unicode[STIX]{x1D719}_{\infty })-\boldsymbol{V}_{\infty }^{(0)}\quad \text{at }r=1,\\ \boldsymbol{v}^{(0)}\, & =\, & HaZ_{w}\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}\quad \text{at walls},\\ \boldsymbol{v}^{(0)}\, & \rightarrow \, & \mathbf{0}\quad \text{as }r\rightarrow \infty ,\end{array}\right\}\end{eqnarray}$$

and the $O(Re_{p})$ problem as:

(2.29) $$\begin{eqnarray}\left.\begin{array}{@{}rcl@{}}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{v}^{(1)}\, & =\, & 0,\\ \unicode[STIX]{x1D6FB}^{2}\boldsymbol{v}^{(1)}-\unicode[STIX]{x1D735}p^{(1)}\, & =\, & \boldsymbol{v}^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}^{(0)}+\boldsymbol{V}_{\infty }^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}^{(0)}+\boldsymbol{v}^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{V}_{\infty }^{(0)},\\ \boldsymbol{v}^{(1)}\, & =\, & \boldsymbol{U}_{s}^{(1)}+\unicode[STIX]{x1D734}_{s}^{(1)}\times \boldsymbol{r}\quad \text{at }r=1,\\ \boldsymbol{v}^{(1)}\, & =\, & \mathbf{0}\quad \text{at walls},\\ \boldsymbol{v}^{(1)}\, & \rightarrow \, & \mathbf{0}\quad \text{as }r\rightarrow \infty .\end{array}\right\}\end{eqnarray}$$

We do not perform a similar expansion for the electrostatic potential because the problem governing electrostatics is decoupled from the flow field.

Owing to (2.27), the hydrodynamic force and torque can be expanded as

(2.30a,b ) $$\begin{eqnarray}\boldsymbol{F}_{H}=\boldsymbol{F}_{H}^{(0)}+Re_{p}\boldsymbol{F}_{H}^{(1)}\quad \text{and}\quad \boldsymbol{L}_{H}=\boldsymbol{L}_{H}^{(0)}+Re_{p}\boldsymbol{L}_{H}^{(1)}.\end{eqnarray}$$

Here, $\boldsymbol{F}_{H}^{(0)}$ represents the hydrodynamic force in the Stokes regime and therefore acts in the $x$ -direction alone. As the flow is two-dimensional, the hydrodynamic force due to inertia ( $\boldsymbol{F}_{H}^{(1)}$ ) is of the following form: $\{F_{x}^{(1)},0,F_{z}^{(1)}\}$ . The cross-stream inertial migration arises from $F_{z}^{(1)}$ , whose evaluation is the primary objective of this work. One way to obtain this is by solving (2.28) and (2.29), and evaluating $Re_{p}\,\boldsymbol{e}_{z}\boldsymbol{\cdot }\int _{S_{p}}\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{H}^{(1)}\,\text{d}S$ . Alternatively, an application of the Lorentz reciprocal theorem allows us to determine the inertial lift force ( $F_{I}\equiv Re_{p}F_{z}^{(1)}$ ) associated with $\boldsymbol{v}^{(1)}$ , without solving for (2.29). In the next section, we will elaborate on this approach which was proposed originally by Ho & Leal (Reference Ho and Leal1974).

2.4 Lift force

The reciprocal theorem relates the properties of an unknown Stokes flow ( $\unicode[STIX]{x1D748},\boldsymbol{v}$ ) to a known test flow field ( $\unicode[STIX]{x1D748}^{t},\boldsymbol{u}^{t}$ ), provided both fields correspond to the same geometry. The test field is taken to be that generated by a sphere moving in the positive $z$ -direction with unit velocity $\boldsymbol{e}_{z}$ in a quiescent fluid between the walls. The test field is governed by

(2.31) $$\begin{eqnarray}\left.\begin{array}{@{}rcl@{}}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{u}^{t}\, & =\, & 0,\quad \unicode[STIX]{x1D6FB}^{2}\boldsymbol{u}^{t}-\unicode[STIX]{x1D735}p^{t}=\mathbf{0},\\ \boldsymbol{u}^{t}\, & =\, & \boldsymbol{e}_{z}\quad \text{at }r=1,\\ \boldsymbol{u}^{t}\, & =\, & \mathbf{0}\quad \text{at the walls,}\\ \boldsymbol{u}^{t}\, & \rightarrow \, & \mathbf{0}\quad \text{at r}\rightarrow \infty .\end{array}\right\}\end{eqnarray}$$

The generalized reciprocal theorem (Kim & Karrila Reference Kim and Karrila2013) states

(2.32) $$\begin{eqnarray}\int _{S_{p}}\boldsymbol{v}\boldsymbol{\cdot }(\unicode[STIX]{x1D748}^{t}\boldsymbol{\cdot }\boldsymbol{n}^{t})\,\text{d}S+\int _{V_{f}}\boldsymbol{v}\boldsymbol{\cdot }(\unicode[STIX]{x1D735}\boldsymbol{\cdot }\unicode[STIX]{x1D748}^{t})\,\text{d}V=\int _{S_{p}}\boldsymbol{u}^{t}\boldsymbol{\cdot }(\unicode[STIX]{x1D748}\boldsymbol{\cdot }\boldsymbol{n})\,\text{d}S+\int _{V_{f}}\boldsymbol{u}^{t}\boldsymbol{\cdot }(\unicode[STIX]{x1D735}\boldsymbol{\cdot }\unicode[STIX]{x1D748})\,\text{d}V.\end{eqnarray}$$

Here $\unicode[STIX]{x1D748}^{t}$ and $\unicode[STIX]{x1D748}$ are the stress tensors corresponding to the test Stokes field and unknown Stokes field. The Navier–Stokes equations (2.29) and (2.31) are expressed in terms of stress tensors as

(2.33a,b ) $$\begin{eqnarray}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{H}^{(1)}=\boldsymbol{v}^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}^{(0)}+\boldsymbol{V}_{\infty }^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}^{(0)}+\boldsymbol{v}^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{V}_{\infty }^{(0)},\quad \text{and}\quad \unicode[STIX]{x1D735}\boldsymbol{\cdot }\unicode[STIX]{x1D748}^{t}=\mathbf{0}.\end{eqnarray}$$

Substituting $\unicode[STIX]{x1D748}_{H}^{(1)}$ as $\unicode[STIX]{x1D748}$ in (2.32) and using the boundary conditions expressed in (2.29), we obtain

(2.34) $$\begin{eqnarray}\displaystyle & & \displaystyle {\boldsymbol{U}_{s}}^{(1)}\boldsymbol{\cdot }\int _{S_{p}}(\unicode[STIX]{x1D748}^{t}\boldsymbol{\cdot }\boldsymbol{n}^{t})\,\text{d}S+\int _{S_{p}}({\unicode[STIX]{x1D734}_{s}}^{(1)}\times \boldsymbol{r})\boldsymbol{\cdot }(\unicode[STIX]{x1D748}^{t}\boldsymbol{\cdot }\boldsymbol{n}^{t})\nonumber\\ \displaystyle & & \displaystyle \quad =\boldsymbol{e}_{z}\boldsymbol{\cdot }\int _{S_{p}}(\unicode[STIX]{x1D748}_{H}^{(1)}\boldsymbol{\cdot }\boldsymbol{n})\,\text{d}S+\int _{V_{f}}\boldsymbol{u}^{t}\boldsymbol{\cdot }(\boldsymbol{v}^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}^{(0)}+\boldsymbol{V}_{\infty }^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}^{(0)}+\boldsymbol{v}^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{V}_{\infty }^{(0)})\,\text{d}V.\qquad \quad\end{eqnarray}$$

The surface integral in the first term on the left-hand side denotes the hydrodynamic force on the sphere due to the $z$ -direction motion ${\approx}-6\unicode[STIX]{x03C0}(1+O(\unicode[STIX]{x1D705}))\boldsymbol{e}_{z}$ (with first-order wall correction). The second term can be shown to be zero by invoking symmetry arguments. Also, since the particle is freely suspended and neutrally buoyant, the first term on the right-hand side is zero. This yields the following expression for the migration velocity of the particle due to inertia:

(2.35) $$\begin{eqnarray}U_{sz}^{(1)}=\frac{-1}{6\unicode[STIX]{x03C0}(1+O(\unicode[STIX]{x1D705}))}\int _{V_{f}}\boldsymbol{u}^{t}\boldsymbol{\cdot }(\boldsymbol{v}^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}^{(0)}+\boldsymbol{V}_{\infty }^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}^{(0)}+\boldsymbol{v}^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{V}_{\infty }^{(0)})\,\text{d}V.\end{eqnarray}$$

Following Ho & Leal (Reference Ho and Leal1974), at the present order of approximation (for migration of $O(Re_{p})$ ), we alternatively prescribe $U_{sz}\equiv 0$ in (2.34). In other words, the particle is not allowed to migrate across streamlines. (Since the particle is free to move in the flow direction, at $O(Re_{p}^{0})$ the problem remains force-free in $x$ -direction and torque-free in $y$ -direction (Ho & Leal Reference Ho and Leal1974).) This implies that a finite inertial force $\boldsymbol{F}_{I}$ acts on the particle

(2.36) $$\begin{eqnarray}\displaystyle F_{I} & \equiv & \displaystyle Re_{p}\left(\boldsymbol{e}_{z}\boldsymbol{\cdot }\int _{S_{p}}(\unicode[STIX]{x1D748}_{H}^{(1)}\boldsymbol{\cdot }\boldsymbol{n})\,\text{d}S\right)\nonumber\\ \displaystyle & = & \displaystyle -Re_{p}\int _{V_{f}}\boldsymbol{u}^{t}\boldsymbol{\cdot }(\boldsymbol{v}^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}^{(0)}+\boldsymbol{V}_{\infty }^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}^{(0)}+\boldsymbol{v}^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{V}_{\infty }^{(0)})\,\text{d}V.\end{eqnarray}$$

We have now obtained the inertia-induced lift force as a volume integral which can be evaluated by solving (2.28) (equations governing the creeping flow $\boldsymbol{v}^{(0)}$ ), equations (2.15)–(2.18) (equations governing the electrostatic potential $\unicode[STIX]{x1D713}$ ) and (2.31) (equations governing the test field). In the next section, we evaluate the disturbance fields and the test field.

3 Evaluation of disturbances

In this work, the disturbance potential ( $\unicode[STIX]{x1D713}$ ) is independent of the hydrodynamics. It affects the hydrodynamics through the slip conditions at the particle and wall surfaces (see (2.28)). Therefore, the electrostatic potential is evaluated first.

3.1 Electrostatic potential

When the particle is not too close to the wall ( $\unicode[STIX]{x1D705}/s\ll 1$ ), the solution can be sought in terms of successive reflections (Brenner Reference Brenner1962). The first reflection represents the disturbance due to a particle in an unbounded domain. The second reflection corrects the previous disturbance by imposing the boundary condition at the walls and ignoring the particle. Subsequently, each reflection imposes the boundary condition alternatively at the particle and walls. Every successive pair of reflections increases the accuracy by $O(\unicode[STIX]{x1D705})$ (Happel & Brenner Reference Happel and Brenner2012). This iterative process is performed until a desired accuracy is attained. We seek the disturbance potential as a sum of reflections

(3.1) $$\begin{eqnarray}\unicode[STIX]{x1D713}=\unicode[STIX]{x1D713}_{1}+\unicode[STIX]{x1D713}_{2}+\cdots \,.\end{eqnarray}$$

Here, $\unicode[STIX]{x1D713}_{i}$ represents the $i$ th reflection. Substituting this in (2.15)–(2.18), we obtain for the first reflection

(3.2) $$\begin{eqnarray}\left.\begin{array}{@{}rcl@{}}\unicode[STIX]{x1D6FB}^{2}\unicode[STIX]{x1D713}_{1}\, & =\, & 0,\\ \boldsymbol{e}_{r}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}_{1}\, & =\, & -\boldsymbol{e}_{r}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{\infty }\quad \text{at }r=1,\\ \unicode[STIX]{x1D713}_{1}\, & \rightarrow \, & 0\quad \text{as }r\rightarrow \infty ,\end{array}\right\}\end{eqnarray}$$

and for the second reflection

(3.3) $$\begin{eqnarray}\left.\begin{array}{@{}rcl@{}}\unicode[STIX]{x1D6FB}^{2}\unicode[STIX]{x1D713}_{2}\, & =\, & 0,\\ \boldsymbol{e}_{z}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}_{2}\, & =\, & -\boldsymbol{e}_{z}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}_{1}\quad \text{at walls.}\end{array}\right\}\end{eqnarray}$$

Solution to $\unicode[STIX]{x1D713}_{1}$ . Equation (3.2) suggests that $\unicode[STIX]{x1D713}_{1}$ is a harmonic function which decays as $r\rightarrow \infty$ . The boundary condition suggests that it must be linear in the ‘driving force’: $\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{\infty }(=-\boldsymbol{e}_{x})$ . Therefore, the solution is sought in terms of spherical solid harmonics (Guazzelli & Morris Reference Guazzelli and Morris2011) as

(3.4) $$\begin{eqnarray}\unicode[STIX]{x1D713}_{1}=\frac{1}{2}\frac{\boldsymbol{r}}{r^{3}}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{\infty }=-\frac{1}{2}\frac{x}{r^{3}}.\end{eqnarray}$$

Solution to $\unicode[STIX]{x1D713}_{2}$ . To evaluate $\unicode[STIX]{x1D713}_{2}$ , we adopt the approach devised by Faxén (Reference Faxén1922) in the context of bounded viscous flows. Using this, the disturbance around the particle is expressed in an integral form which satisfies the boundary conditions at the walls. The first reflection is characterized by particle scale ( $a^{\prime }$ ). The second reflection $\unicode[STIX]{x1D713}_{2}$ is characterized by a length scale ( $l^{\prime }$ ) which is $O(1/\unicode[STIX]{x1D705})$ , because the walls are remotely located. Therefore, the coordinates for second reflection are stretched, and are termed as ‘outer’ coordinates. These outer coordinates (denoted by capital letters) are defined as

(3.5a-d ) $$\begin{eqnarray}R=r\unicode[STIX]{x1D705}\quad X=x\unicode[STIX]{x1D705}\quad Y=y\unicode[STIX]{x1D705}\quad Z=z\unicode[STIX]{x1D705}.\end{eqnarray}$$

Using Faxén’s transformations (see § A.2), we obtain the second reflection

(3.6) $$\begin{eqnarray}\tilde{\unicode[STIX]{x1D713}}_{2}=\frac{\unicode[STIX]{x1D705}^{2}}{2\unicode[STIX]{x03C0}}\int _{-\infty }^{+\infty }\int _{-\infty }^{+\infty }\text{e}^{\text{i}\unicode[STIX]{x1D6E9}}(\text{e}^{(-\unicode[STIX]{x1D706}Z/2)}b_{2}+\text{e}^{(+\unicode[STIX]{x1D706}Z/2)}b_{3})\left(\frac{\text{i}\unicode[STIX]{x1D709}}{\unicode[STIX]{x1D706}}\right)\,\text{d}\unicode[STIX]{x1D709}\,\text{d}\unicode[STIX]{x1D702}.\end{eqnarray}$$

Here $b_{2}$ and $b_{3}$ are

(3.7a,b ) $$\begin{eqnarray}b_{2}=\frac{1}{8}\frac{(1+\text{e}^{(1-s)\unicode[STIX]{x1D706}})}{-1+\text{e}^{\unicode[STIX]{x1D706}}},\quad b_{3}=\frac{1}{8}\frac{(1+\text{e}^{s\unicode[STIX]{x1D706}})}{-1+\text{e}^{\unicode[STIX]{x1D706}}}.\end{eqnarray}$$

The next reflection ( $\unicode[STIX]{x1D713}_{3}$ ) is $O(\unicode[STIX]{x1D705}^{3})$ . As we restrict $\unicode[STIX]{x1D705}\ll 1$ , the first two reflections capture the leading-order contribution to the disturbance potential.

Solution of $\boldsymbol{F}_{M}$ and $\boldsymbol{L}_{M}$ . Before determining the inertial lift $F_{I}$ through the evaluation of velocity disturbances in the creeping flow limit, we find the electrical force and torque on the particle caused by Maxwell stress. These are used later in the calculation of $\boldsymbol{U}_{s}^{(0)}$ and $\unicode[STIX]{x1D734}_{s}^{(0)}$ (see § 3.3).

We substitute (3.4) and (3.6) in both (2.24) and (2.25). Upon simplification (see § A.3) we obtain

(3.8) $$\begin{eqnarray}\displaystyle & \displaystyle \boldsymbol{F}_{M}=4\unicode[STIX]{x03C0}Ha\left(\frac{3\unicode[STIX]{x03C0}}{16}\unicode[STIX]{x1D705}^{4}(\mathfrak{Z}(4,s)-\mathfrak{Z}(4,1-s))\right)\boldsymbol{e}_{z}+O(\unicode[STIX]{x1D705}^{7}), & \displaystyle\end{eqnarray}$$
(3.9) $$\begin{eqnarray}\displaystyle & \displaystyle \boldsymbol{L}_{M}=\mathbf{0}. & \displaystyle\end{eqnarray}$$

Here, $\mathfrak{Z}$ is the generalized Riemann zeta function (Abramowitz & Stegen Reference Abramowitz and Stegen1972). This leading-order electrical force acts only in the $z$ -direction and always away from the walls (i.e. positive below the channel centreline and vice versa). As the particle approaches walls ( $s\rightarrow 0$ or 1), equation (3.8) asymptotically matches with the single wall expression derived by Yariv (Reference Yariv2006). We also find that the Maxwell stresses exert no torque on the particle, at the present level of approximation.

Having obtained the leading-order potential distribution, we next evaluate the velocity disturbance.

3.2 Velocity disturbance

We seek the disturbance ( $\boldsymbol{v}^{(0)},p^{(0)}$ ) as successive reflections

(3.10a,b ) $$\begin{eqnarray}\boldsymbol{v}^{(0)}=\boldsymbol{v}_{1}^{(0)}+\boldsymbol{v}_{2}^{(0)}+\boldsymbol{v}_{3}^{(0)}+\cdots \,,\quad p^{(0)}=p_{1}^{(0)}+p_{2}^{(0)}+p_{3}^{(0)}+\cdots \,.\end{eqnarray}$$

Upon substituting the above expansion in (2.28), we obtain the following set of problems:

(3.11) $$\begin{eqnarray}\left.\begin{array}{@{}rcl@{}}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{v}_{1}^{(0)}\, & =\, & 0,\quad \unicode[STIX]{x1D6FB}^{2}\boldsymbol{v}_{1}^{(0)}-\unicode[STIX]{x1D735}p_{1}^{(0)}=\mathbf{0},\\ \boldsymbol{v}_{1}^{(0)}\, & =\, & U_{sx}^{(0)}\boldsymbol{e}_{x}+\unicode[STIX]{x1D6FA}_{sy}^{(0)}\boldsymbol{e}_{y}\times \boldsymbol{r}+HaZ_{p}(\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}_{1}+\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}_{2})\\ \, & \, & -(\unicode[STIX]{x1D6FC}+\unicode[STIX]{x1D6FD}z+\unicode[STIX]{x1D6FE}z^{2}+Ha(Z_{p}-Z_{w}))\boldsymbol{e}_{x}\quad \text{at }r=1,\\ \boldsymbol{v}_{1}^{(0)}\, & \rightarrow \, & \mathbf{0}\quad \text{at }r\rightarrow \infty .\end{array}\right\}\end{eqnarray}$$
(3.12) $$\begin{eqnarray}\left.\begin{array}{@{}rcl@{}}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{v}_{2}^{(0)}\, & =\, & 0,\quad \unicode[STIX]{x1D6FB}^{2}\boldsymbol{v}_{2}^{(0)}-\unicode[STIX]{x1D735}p_{2}^{(0)}=\mathbf{0},\\ \boldsymbol{v}_{2}^{(0)}\, & =\, & HaZ_{w}(\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}_{1}+\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}_{2})-\boldsymbol{v}_{1}^{(0)}\quad \text{at the walls,}\\ \boldsymbol{v}_{2}^{(0)}\, & \rightarrow \, & \mathbf{0}\quad \text{at }r\rightarrow \infty .\end{array}\right\}\end{eqnarray}$$
(3.13) $$\begin{eqnarray}\left.\begin{array}{@{}rcl@{}}\unicode[STIX]{x1D735}\boldsymbol{\cdot }\boldsymbol{v}_{3}^{(0)}\, & =\, & 0,\quad \unicode[STIX]{x1D6FB}^{2}\boldsymbol{v}_{3}^{(0)}-\unicode[STIX]{x1D735}p_{3}^{(0)}=\mathbf{0},\\ \boldsymbol{v}_{3}^{(0)}\, & =\, & -\boldsymbol{v}_{2}^{(0)}\quad \text{at }r=1,\\ \boldsymbol{v}_{3}^{(0)}\, & \rightarrow \, & \mathbf{0}\quad \text{at }r\rightarrow \infty .\end{array}\right\}\end{eqnarray}$$

Solution of $\boldsymbol{v}_{1}^{(0)}$ . The odd reflections are found using Lamb’s general method (Lamb Reference Lamb1975). We obtain the following leading terms for $\boldsymbol{v}_{1}^{(0)}$ :

(3.14) $$\begin{eqnarray}\boldsymbol{v}_{1}^{(0)}=A_{1}\left(\boldsymbol{e}_{x}+\frac{x\boldsymbol{r}}{r^{2}}\right)\frac{1}{r}+B_{1}\left(-\boldsymbol{e}_{x}+\frac{3x\boldsymbol{r}}{r^{2}}\right)\frac{1}{r^{3}}+C_{1}\left(\frac{z\boldsymbol{e}_{x}}{r^{3}}-\frac{x\boldsymbol{e}_{z}}{r^{3}}\right)+D_{1}\left(\frac{zx\boldsymbol{r}}{r^{5}}\right).\end{eqnarray}$$

The coefficients $A_{1}$ , $B_{1}$ , $C_{1}$ and $D_{1}$ are associated with the Stokeslet, source-dipole, rotlet (generated due to relative rotation of the particle) and stresslet flow disturbances, respectively. These are

(3.15) $$\begin{eqnarray}\left.\begin{array}{@{}c@{}}A_{1}={\displaystyle \frac{3}{4}}\left(U_{sx}^{(0)}-\unicode[STIX]{x1D6FC}-{\displaystyle \frac{\unicode[STIX]{x1D6FE}}{3}}-Ha(Z_{p}-Z_{w})+\unicode[STIX]{x1D705}^{3}HaZ_{p}\hspace{2.22198pt}\mathfrak{s}_{x}(\tilde{\unicode[STIX]{x1D713}}_{2})\right),\\ B_{1}={\displaystyle \frac{1}{2}}(HaZ_{p})-{\displaystyle \frac{1}{4}}\left(U_{sx}^{(0)}-\unicode[STIX]{x1D6FC}-{\displaystyle \frac{3\unicode[STIX]{x1D6FE}}{5}}-Ha(Z_{p}-Z_{w})+\unicode[STIX]{x1D705}^{3}HaZ_{p}\hspace{2.22198pt}\mathfrak{s}_{x}(\tilde{\unicode[STIX]{x1D713}}_{2})\right),\\ C_{1}=\unicode[STIX]{x1D6FA}_{sy}^{(0)}-\unicode[STIX]{x1D6FD}/2,\quad \text{and}\quad D_{1}=-5\unicode[STIX]{x1D6FD}/2.\end{array}\right\}\end{eqnarray}$$

Here, $\boldsymbol{\mathfrak{s}}(\tilde{\unicode[STIX]{x1D713}}_{2})$ is a vector denoting the contribution to slip at the particle surface due to the wall correction of the disturbance potential. This correction enters the solution at $O(\unicode[STIX]{x1D705}^{3})$ .

(3.16) $$\begin{eqnarray}\boldsymbol{\mathfrak{s}}(\tilde{\unicode[STIX]{x1D713}}_{2})=\int _{0}^{\infty }-{\textstyle \frac{1}{4}}(b_{2}+b_{3})\unicode[STIX]{x1D706}^{2}\,\text{d}\unicode[STIX]{x1D706}\boldsymbol{e}_{x}.\end{eqnarray}$$

Solution to $\boldsymbol{v}_{2}^{(0)}$ . Similar to § 3.1, we use Faxén transformation technique to obtain the solution to $\tilde{\boldsymbol{v}}_{2}^{(0)}=\{\tilde{u} _{2}^{(0)},\tilde{v}_{2}^{(0)},\tilde{w}_{2}^{(0)}\}$ as

(3.17) $$\begin{eqnarray}\tilde{u} _{2}^{(0)}=\frac{1}{2\unicode[STIX]{x03C0}}\int _{-\infty }^{+\infty }\int _{-\infty }^{+\infty }\text{e}^{\text{i}\unicode[STIX]{x1D6E9}}\left(\begin{array}{@{}c@{}}\text{e}^{(-\unicode[STIX]{x1D706}Z/2)}\left(\ell _{4}+{\displaystyle \frac{\unicode[STIX]{x1D709}^{2}}{\unicode[STIX]{x1D706}^{2}}}\left(\ell _{5}+{\displaystyle \frac{\unicode[STIX]{x1D706}Z}{2}}\ell _{6}-{\displaystyle \frac{HaZ_{w}\unicode[STIX]{x1D705}^{3}\unicode[STIX]{x1D706}}{2}}b_{2}\right)\right)\\ +\,\text{e}^{(+\unicode[STIX]{x1D706}Z/2)}\left(\ell _{7}+{\displaystyle \frac{\unicode[STIX]{x1D709}^{2}}{\unicode[STIX]{x1D706}^{2}}}\left(\ell _{8}-{\displaystyle \frac{\unicode[STIX]{x1D706}Z}{2}}\ell _{9}-{\displaystyle \frac{HaZ_{w}\unicode[STIX]{x1D705}^{3}\unicode[STIX]{x1D706}}{2}}b_{3}\right)\right)\end{array}\right)\text{d}\unicode[STIX]{x1D709}\,\text{d}\unicode[STIX]{x1D702},\end{eqnarray}$$
(3.18) $$\begin{eqnarray}\tilde{v}_{2}^{(0)}=\frac{1}{2\unicode[STIX]{x03C0}}\int _{-\infty }^{+\infty }\int _{-\infty }^{+\infty }\text{e}^{\text{i}\unicode[STIX]{x1D6E9}}\left(\begin{array}{@{}c@{}}\text{e}^{(-\unicode[STIX]{x1D706}Z/2)}\left(\ell _{5}+{\displaystyle \frac{\unicode[STIX]{x1D706}Z}{2}}\ell _{6}-{\displaystyle \frac{HaZ_{w}\unicode[STIX]{x1D705}^{3}\unicode[STIX]{x1D706}}{2}}b_{2}\right)\\ +\,\text{e}^{(+\unicode[STIX]{x1D706}Z/2)}\left(\ell _{8}-{\displaystyle \frac{\unicode[STIX]{x1D706}Z}{2}}\ell _{9}-{\displaystyle \frac{HaZ_{w}\unicode[STIX]{x1D705}^{3}\unicode[STIX]{x1D706}}{2}}b_{3}\right)\end{array}\right)\left(\frac{\unicode[STIX]{x1D709}\unicode[STIX]{x1D702}}{\unicode[STIX]{x1D706}^{2}}\right)\text{d}\unicode[STIX]{x1D709}\,\text{d}\unicode[STIX]{x1D702},\end{eqnarray}$$
(3.19) $$\begin{eqnarray}\displaystyle \tilde{w}_{2}^{(0)} & = & \displaystyle \frac{1}{2\unicode[STIX]{x03C0}}\int _{-\infty }^{+\infty }\int _{-\infty }^{+\infty }\text{e}^{\text{i}\unicode[STIX]{x1D6E9}}\left(\begin{array}{@{}c@{}}\text{e}^{(-\unicode[STIX]{x1D706}Z/2)}\left(\ell _{4}+\ell _{5}+\left(1+{\displaystyle \frac{\unicode[STIX]{x1D706}Z}{2}}\right)\ell _{6}-{\displaystyle \frac{HaZ_{w}\unicode[STIX]{x1D705}^{3}\unicode[STIX]{x1D706}Z}{2}}b_{2}\right)\\ -\,\text{e}^{(+\unicode[STIX]{x1D706}Z/2)}\left(\ell _{7}+\ell _{8}+\left(1-{\displaystyle \frac{\unicode[STIX]{x1D706}Z}{2}}\right)\ell _{9}-{\displaystyle \frac{HaZ_{w}\unicode[STIX]{x1D705}^{3}\unicode[STIX]{x1D706}Z}{2}}b_{3}\right)\end{array}\right)\nonumber\\ \displaystyle & & \displaystyle \times \,\left(\frac{\text{i}\unicode[STIX]{x1D709}}{\unicode[STIX]{x1D706}}\right)\text{d}\unicode[STIX]{x1D709}\,\text{d}\unicode[STIX]{x1D702}.\end{eqnarray}$$

Here, the terms $\ell _{4},\ell _{5},\ldots ,\ell _{9}$ are functions of the Fourier variable $\unicode[STIX]{x1D706}$ and the coefficients ( $A_{1}$ , $B_{1}$ , $C_{1}$ and $D_{1}$ ), defined in (3.15). Details of the derivation are skipped for brevity and can be found in the supplementary material.

At the leading order, it suffices to represent the velocity disturbance field using the first two reflections. However, the solution is incomplete because the translational and angular velocities are unknown (see (3.15)). These can be found by imposing force-free and torque-free conditions on the particle at $O(Re^{0})$ : $\boldsymbol{F}_{H}^{(0)}+\boldsymbol{F}_{M}=\mathbf{0}$ and $\boldsymbol{L}_{H}^{(0)}+\boldsymbol{L}_{M}=\mathbf{0}$ . Since the electric force (3.8) acts only along the $z$ -axis and the electric torque (3.9) is zero, $U_{s\,x}^{(0)}$ and $\unicode[STIX]{x1D6FA}_{s\,y}^{(0)}$ are found by hydrodynamic force and torque balance in $x$ and $y$ directions, respectively.

3.3 Evaluation of $\boldsymbol{U}_{s}^{(0)}$ and $\unicode[STIX]{x1D734}_{s}^{(0)}$

For a particle–wall system, Happel & Brenner (Reference Happel and Brenner2012, p. 239) derived the hydrodynamic force and torque on a spherical particle in terms of successive reflections

(3.20a,b ) $$\begin{eqnarray}\boldsymbol{F}_{H}^{(0)}=\boldsymbol{F}_{H\,1}^{(0)}+\boldsymbol{F}_{H\,3}^{(0)}+\cdots \quad \text{and}\quad \boldsymbol{L}_{H}^{(0)}=\boldsymbol{L}_{H\,1}^{(0)}+\boldsymbol{L}_{H\,3}^{(0)}+\cdots \,.\end{eqnarray}$$

Since the particle is absent in the formulation of even-numbered reflections, the hydrodynamic drag and torque due to even fields vanishes. Thus, the contribution to force and torque arises only from the odd-numbered reflections.

At the current order of reflections of the velocity disturbance field ( $\boldsymbol{v}^{(0)}=\boldsymbol{v}_{1}^{(0)}+\boldsymbol{v}_{2}^{(0)}$ ), imposing force-free and torque-free conditions provides translational and rotational velocities without the wall correction. $\boldsymbol{F}_{H\,3}^{(0)}$ incorporates the first-order wall effects into $U_{s\,x}^{(0)}$ and $\unicode[STIX]{x1D6FA}_{s\,y}^{(0)}$ , which requires $\boldsymbol{v}_{3}^{(0)}$ . Section A.4 describes the determination of $\boldsymbol{v}_{3}^{(0)}$ using Lamb’s general solution (Lamb Reference Lamb1975).

The force and torque on a spherical particle can be expressed through the coefficients of Stokeslet and rotlet disturbances, respectively. Following Kim & Karrila (Reference Kim and Karrila2013, p. 88), we write (3.20) as

(3.21a,b ) $$\begin{eqnarray}F_{H\,x}^{(0)}=-4\unicode[STIX]{x03C0}(A_{1}+A_{3}+\cdots )\quad \text{and}\quad L_{Hy}^{(0)}=-8\unicode[STIX]{x03C0}(C_{1}+C_{3}+\cdots ).\end{eqnarray}$$

The coefficients $A_{1},C_{1}$ and $A_{3},C_{3}$ are associated with Lamb’s solution of the first reflection of the velocity disturbance (3.14) and third reflection (see (A 17)), respectively. $A_{3}$ and $C_{3}$ can be expressed in terms of $A_{1}$ , $B_{1}$ , $C_{1}$ and $D_{1}$ as

(3.22) $$\begin{eqnarray}\displaystyle & A_{3}=A_{1}(\unicode[STIX]{x1D705}W_{A})+B_{1}(\unicode[STIX]{x1D705}^{3}W_{B})+C_{1}(\unicode[STIX]{x1D705}^{2}W_{C})+D_{1}(\unicode[STIX]{x1D705}^{2}W_{D})-{\textstyle \frac{3}{4}}\unicode[STIX]{x1D705}^{3}HaZ_{w}\hspace{2.22198pt}\mathfrak{s}_{x}(\tilde{\unicode[STIX]{x1D713}}_{2}), & \displaystyle\end{eqnarray}$$
(3.23) $$\begin{eqnarray}\displaystyle & C_{3}=A_{1}(\unicode[STIX]{x1D705}^{2}{\mathcal{X}}_{A})+B_{1}(\unicode[STIX]{x1D705}^{3}{\mathcal{X}}_{B})+C_{1}(\unicode[STIX]{x1D705}^{4}{\mathcal{X}}_{C}). & \displaystyle\end{eqnarray}$$

Here, $\unicode[STIX]{x1D705}W_{A},\unicode[STIX]{x1D705}^{3}W_{B},\unicode[STIX]{x1D705}^{2}W_{C}$ and $\unicode[STIX]{x1D705}^{2}W_{D}$ represent the wall corrections to hydrodynamic drag due to the reflection of Stokeslet, source-dipole, rotlet and stresslet disturbances, respectively. Similarly, $\unicode[STIX]{x1D705}^{2}{\mathcal{X}}_{A}$ , $\unicode[STIX]{x1D705}^{3}{\mathcal{X}}_{B}$ and $\unicode[STIX]{x1D705}^{4}{\mathcal{X}}_{C}$ represent the wall correction to hydrodynamic torque. These corrections are integrals over Fourier variable $\unicode[STIX]{x1D706}$ and are a function of distance from the walls.

Substitution of (3.22) and (3.23) into (3.21) results in a system of two equations for: $U_{s\,x}^{(0)}$ and $\unicode[STIX]{x1D6FA}_{s\,y}^{(0)}$ . Imposing the hydrodynamic force and torque to be zero and upon expanding the coefficients $A_{1}$ , $B_{1}$ , $C_{1}$ and $D_{1}$ , we obtain

(3.24) $$\begin{eqnarray}U_{s\,x}^{(0)}\approx \left\{\begin{array}{@{}l@{}}[(\unicode[STIX]{x1D6FC}+\unicode[STIX]{x1D6FE}/3)(1+\unicode[STIX]{x1D705}W_{A})-10\unicode[STIX]{x1D705}^{2}\unicode[STIX]{x1D6FD}W_{D}/9]/(1+\unicode[STIX]{x1D705}W_{A})\quad \\ \quad +\,Ha(Z_{p}-Z_{w})\left(1-{\displaystyle \frac{2}{3}}{\displaystyle \frac{W_{B}\unicode[STIX]{x1D705}^{3}}{(1+\unicode[STIX]{x1D705}W_{A})}}\right)-\unicode[STIX]{x1D705}^{3}\hspace{2.22198pt}\mathfrak{s}_{x}(\tilde{\unicode[STIX]{x1D713}}_{2})Ha\left(Z_{p}-{\displaystyle \frac{Z_{w}}{(1+\unicode[STIX]{x1D705}W_{A})}}\right),\quad \end{array}\right.\end{eqnarray}$$
(3.25) $$\begin{eqnarray}\unicode[STIX]{x1D6FA}_{s\,y}^{(0)}\approx \frac{\unicode[STIX]{x1D6FD}(1+\unicode[STIX]{x1D705}W_{A})-10{\mathcal{X}}_{D}\unicode[STIX]{x1D705}^{3}\unicode[STIX]{x1D6FD}/3}{2(1+\unicode[STIX]{x1D705}W_{A})}-Ha(Z_{p}-Z_{w})\frac{{\mathcal{X}}_{B}\unicode[STIX]{x1D705}^{4}}{2(1+{\mathcal{X}}_{C}\unicode[STIX]{x1D705}^{3})}.\end{eqnarray}$$

Validation of the above two velocities with the literature can be found in appendix B.

With (3.14), (3.17)–(3.19), (3.24) and (3.25), we have obtained the solution to $\boldsymbol{v}^{(0)}$ . We use a similar procedure to evaluate the test field $\boldsymbol{u}^{t}$ governed by (2.31) (the details are described in § A.5). The calculation of the inertial lift force using the disturbance and test field is discussed next.

4 Inertial force volume integral

In § 3.1, we found that the electrical force $\boldsymbol{F}_{M}$ acts in the lateral direction (see (3.8)). The total lateral force experienced by an electrophoretic particle arises from inertial stresses ( $F_{I}$ ) and Maxwell stresses ( $F_{M\,z}$ ). Since the primary objective of this work is to determine lateral migration due to inertia, we now focus on $F_{I}$ . Later, in § 9, we compare the contributions from $F_{I}$ and $F_{M\,z}$ .

In § 2, we derived the inertial migration force (2.36) as

(4.1) $$\begin{eqnarray}F_{I}=-Re_{p}\int _{V_{f}}\boldsymbol{u}^{t}\boldsymbol{\cdot }\boldsymbol{f}\,\text{d}V.\end{eqnarray}$$

Here, $\boldsymbol{f}=\boldsymbol{v}^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}^{(0)}+\boldsymbol{V}_{\infty }^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}^{(0)}+\boldsymbol{v}^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{V}_{\infty }^{(0)}$ . Before discussing the evaluation of (4.1), in this section, we draw a few qualitative insights on the behaviour of the lift force integral.

The domain of integration extends from the surface of particle to the walls of the channel. Following Ho & Leal (Reference Ho and Leal1974) and Hood et al. (Reference Hood, Lee and Roper2015), we divide the fluid domain: $V_{f}=V_{1}+V_{2}$ . These sub-domains are defined by

(4.2a,b ) $$\begin{eqnarray}V_{1}=\{\boldsymbol{r}:1\leqslant |r|\leqslant \unicode[STIX]{x1D6FF}\},\quad V_{2}=\{\boldsymbol{R}:\unicode[STIX]{x1D705}\unicode[STIX]{x1D6FF}\leqslant |R|\leqslant \infty \}.\end{eqnarray}$$

Here $\unicode[STIX]{x1D6FF}$ is an intermediate radius which satisfies: $1\ll \unicode[STIX]{x1D6FF}\ll 1/\unicode[STIX]{x1D705}$ . The length scale corresponding to the inner domain ( $V_{1}$ ) is particle radius ‘ $a^{\prime }$ ’. Whereas, channel width ‘ $l^{\prime }$ ’ is the characteristic length in the outer domain ( $V_{2}$ ).

We first inspect and compare the order of magnitude of contributions arising from the volume integrals in the inner and outer domains. Ho & Leal (Reference Ho and Leal1974) and Hood et al. (Reference Hood, Lee and Roper2015), in the absence of electrophoresis, found that the contribution from inner integral was $O(\unicode[STIX]{x1D705})$ smaller than that from the outer integral. Ho & Leal (Reference Ho and Leal1974) hence neglected the contribution from the inner integral. In this section, we show that such a simplification is not justified for the electrophoretic case.

4.1 Inner integral

The order of magnitude of the velocity fields in terms of size ratio $\unicode[STIX]{x1D705}$ and radial distance $r$ , at the leading order are

(4.3a,b ) $$\begin{eqnarray}\boldsymbol{v}_{1}^{(0)}\sim O(1/r^{3})Ha\,Z_{p}+O(\unicode[STIX]{x1D705}/r^{2}),\quad \boldsymbol{v}_{2}^{(0)}\sim O(\unicode[STIX]{x1D705}^{3})+O(\unicode[STIX]{x1D705}^{3})Ha\,(Z_{p}-Z_{w}),\end{eqnarray}$$
(4.4a,b ) $$\begin{eqnarray}\boldsymbol{u}_{1}^{(t)}\sim O(1/r)+O(1/r^{3}),\quad \boldsymbol{u}_{2}^{(t)}\sim O(\unicode[STIX]{x1D705})+O(\unicode[STIX]{x1D705}^{3}).\end{eqnarray}$$

Substituting the translational velocity (3.24) into the undisturbed background flow ( $\boldsymbol{V}_{\infty }^{(0)}=(\unicode[STIX]{x1D6FC}+\unicode[STIX]{x1D6FD}z+\unicode[STIX]{x1D6FE}z^{2})\boldsymbol{e}_{x}+HaZ_{w}\unicode[STIX]{x1D735}\unicode[STIX]{x1D719}_{\infty }-\boldsymbol{U}_{s}^{(0)}$ ), we obtain the order of magnitude of $\boldsymbol{V}_{\infty }^{(0)}$ as

(4.5) $$\begin{eqnarray}\boldsymbol{V}_{\infty }^{(0)}\sim O(\unicode[STIX]{x1D705}r)+O(\unicode[STIX]{x1D705}^{2}r^{2})+O(1)HaZ_{p}+\cdots \,.\end{eqnarray}$$

Using (4.3)–(4.5) in (4.1), we obtain the integrand as

(4.6) $$\begin{eqnarray}\displaystyle \boldsymbol{u}^{t}\boldsymbol{\cdot }\boldsymbol{f} & {\sim} & \displaystyle O\left(\frac{(HaZ_{p})^{2}}{r^{5}}+\frac{(HaZ_{p})^{2}}{r^{7}}+\cdots \right)+\unicode[STIX]{x1D705}O\left(\frac{HaZ_{p}}{r^{4}}+\frac{HaZ_{p}}{r^{6}}+\cdots \right)\nonumber\\ \displaystyle & & \displaystyle +\,\unicode[STIX]{x1D705}^{2}O\left(\frac{1}{r^{3}}+\frac{HaZ_{p}}{r^{5}}+\cdots \right)+\unicode[STIX]{x1D705}^{3}O\left(\frac{1}{r^{2}}+\frac{1}{r^{4}}+\cdots \right)+\cdots \,.\end{eqnarray}$$

The volume integral of the first term is identically zero. The leading-order contribution arises from the second $O(\unicode[STIX]{x1D705})$ term

(4.7) $$\begin{eqnarray}\lim _{\unicode[STIX]{x1D6FF}\rightarrow \infty }F_{V1}=-Re_{p}\left(0+\left(\frac{47\unicode[STIX]{x03C0}}{20}HaZ_{p}\right)\unicode[STIX]{x1D6FD}+0+O(\unicode[STIX]{x1D705}^{3})+\cdots \right).\end{eqnarray}$$

In the above expression, the proportionality of $Ha\,Z_{p}$ suggests that the $O(\unicode[STIX]{x1D705})$ contribution (implicit in background shear $\unicode[STIX]{x1D6FD}$ ) arises due to electrophoresis. The contribution due to stresslet disturbances and wall reflections is $O(\unicode[STIX]{x1D705}^{3})$ . For electric field in the same direction as the flow ( $Ha>0$ ), a positive $Z_{p}$ corresponds to a leading particle. Below the centreline, the shear ( $\unicode[STIX]{x1D6FD}$ ) is positive and the overall expression in (4.7) is therefore negative. This corresponds to a lift in the negative $z$ -direction which pushes the leading particle towards the wall. A similar explanation can be used to show that a lagging particle ( $Z_{p}<0$ ) experiences a lift (4.7) towards the centre. These effects were also experimentally observed by Kim & Yoo (Reference Kim and Yoo2009a ,Reference Kim and Yoo b ), Cevheri & Yoda (Reference Cevheri and Yoda2014), Yuan et al. (Reference Yuan, Pan, Zhang, Yan, Zhao, Alici and Li2016), Li & Xuan (Reference Li and Xuan2018) and Yee & Yoda (Reference Yee and Yoda2018). Expression (4.7) also reveals that the wall zeta potential does not affect the lift because its contribution to the disturbance is $O(\unicode[STIX]{x1D705}^{3})$ (see (4.3)).

In the absence of electrophoresis, the inner integral lift contributes at $O(\unicode[STIX]{x1D705}^{3})$ , as also previously reported by Ho & Leal (Reference Ho and Leal1974) and Hood et al. (Reference Hood, Lee and Roper2015). Next we estimate the contribution arising from the outer integral.

4.2 Outer integral

Since the walls lie at distances $O(1/\unicode[STIX]{x1D705})$ , the velocity field expressions are rescaled with respect to $R(=\unicode[STIX]{x1D705}r)$ (similar to (3.5)). The inertial lift force expression in the outer coordinates is

(4.8) $$\begin{eqnarray}\displaystyle F_{V2} & = & \displaystyle -Re_{p}\int _{V_{2}}(\tilde{\boldsymbol{u}}_{1}^{t}+\tilde{\boldsymbol{u}}_{2}^{t})\boldsymbol{\cdot }\left[\begin{array}{@{}c@{}}(\tilde{\boldsymbol{v}}_{1}^{(0)}+\tilde{\boldsymbol{v}}_{2}^{(0)})\boldsymbol{\cdot }\unicode[STIX]{x1D705}\tilde{\unicode[STIX]{x1D735}}(\tilde{\boldsymbol{v}}_{1}^{(0)}+\tilde{\boldsymbol{v}}_{2}^{(0)})\\ +\,\tilde{\boldsymbol{V}}_{\infty }^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D705}\tilde{\unicode[STIX]{x1D735}}(\tilde{\boldsymbol{v}}_{1}^{(0)}+\tilde{\boldsymbol{v}}_{2}^{(0)})+(\tilde{\boldsymbol{v}}_{1}^{(0)}+\tilde{\boldsymbol{v}}_{2}^{(0)})\boldsymbol{\cdot }\unicode[STIX]{x1D705}\tilde{\unicode[STIX]{x1D735}}\tilde{\boldsymbol{V}}_{\infty }^{(0)}\end{array}\right]\unicode[STIX]{x1D705}^{-3}\,\text{d}\tilde{V}\nonumber\\ \displaystyle & = & \displaystyle -Re_{p}\,\unicode[STIX]{x1D705}^{-2}\int _{V_{2}}\tilde{\boldsymbol{u}}^{t}\boldsymbol{\cdot }\tilde{\boldsymbol{f}}\,\text{d}\tilde{V}.\end{eqnarray}$$

In the outer coordinate representation, the order of magnitude of the velocity fields in terms of size ratio $\unicode[STIX]{x1D705}$ , at the leading order are

(4.9a,b ) $$\begin{eqnarray}\tilde{\boldsymbol{v}}_{1}^{(0)}\sim O(\unicode[STIX]{x1D705}^{3})+O(\unicode[STIX]{x1D705}^{3})Ha\,Z_{p},\quad \tilde{\boldsymbol{v}}_{2}^{(0)}\sim O(\unicode[STIX]{x1D705}^{3})+O(\unicode[STIX]{x1D705}^{3})Ha\,(Z_{p}-Z_{w}),\end{eqnarray}$$
(4.10a,b ) $$\begin{eqnarray}\tilde{\boldsymbol{u}}_{1}^{(t)}\sim O(\unicode[STIX]{x1D705})+O(\unicode[STIX]{x1D705}^{3}),\quad \tilde{\boldsymbol{u}}_{2}^{(t)}\sim O(\unicode[STIX]{x1D705})+O(\unicode[STIX]{x1D705}^{3}).\end{eqnarray}$$

The order of magnitude of the undisturbed background velocity is

(4.11) $$\begin{eqnarray}\tilde{\boldsymbol{V}}_{\infty }\sim O(1)+O(1)HaZ_{p}+O(\unicode[STIX]{x1D705}^{2})+\cdots \,.\end{eqnarray}$$

Substituting (4.9)–(4.11) in (4.8), we find that the integrand is $O(\unicode[STIX]{x1D705}^{2})$ . Since the contributions from the inner and outer integrals are comparable, it is important that the integration must be carried out from the particle surface to the walls.

4.3 Evaluation of volume integral

The region of integration extends from the surface of the spherical particle to the rectangular walls, which extend to infinity in the $x$ and $y$ directions. A direct numerical approach would be computationally intensive as the evaluation of the lift force involves numerous nested Fourier integrals, apart from integrals in $x$ , $y$ and $z$ coordinates. (Faxén transformation provides the wall reflected fields in terms of Fourier integrals, which makes it cumbersome to evaluate the lift force volume integral, as it consists of 7 nested integrals. Using certain transformations we reduce this number to 5. See supplementary material for further details.) For computational convenience, we resort to a splitting of the region over which the integral is evaluated. We perform the integration in two sub-regions, where the region of integration extends from: (i) the spherical surface to a circumscribing cylinder and (ii) the cylindrical surface to the walls ( $z$ -direction) and infinity ( $x$ and $y$ directions). This simplifies the calculation as; in sub-region (i) we employ a spherical coordinate system and evaluate the integral with the help of trigonometric identities; in sub-region (ii) a cylindrical coordinate system is employed to perform the integration. We evaluate the integral in both the sub-regions and include it in our results, which ensures no loss of accuracy.

We choose to evaluate the volume integral in the outer coordinates, over the entire volume ( $V_{f}$ ). For sub-region (ii), the region of integration can be visualized as a cylinder $(Z_{C}\in [-s,1-s]\text{ and }R_{C}\in [0,\infty ))$ excluding an asymptotically small cylindrical ‘cavity’ (radius $\in [0,\unicode[STIX]{x1D705}]$ , height $\in [-\unicode[STIX]{x1D705},\unicode[STIX]{x1D705}]$ ). The velocities are transformed into cylindrical coordinates $(R_{C},\unicode[STIX]{x1D703}_{C},Z_{C})$ . The lift force volume integral corresponding to sub-region (ii) is

(4.12) $$\begin{eqnarray}F_{I}=-Re_{p}\int _{0}^{2\unicode[STIX]{x03C0}}\unicode[STIX]{x1D705}^{-2}\left\{\begin{array}{@{}c@{}}\displaystyle \int _{0}^{\infty }\int _{-s}^{-\unicode[STIX]{x1D705}}\tilde{\boldsymbol{u}}^{t}\boldsymbol{\cdot }\tilde{\boldsymbol{f}}\hspace{2.22198pt}R_{C}\,\text{d}Z_{C}\,\text{d}R_{C}\\ \displaystyle +\int _{\unicode[STIX]{x1D705}}^{\infty }\int _{-\unicode[STIX]{x1D705}}^{+\unicode[STIX]{x1D705}}\tilde{\boldsymbol{u}}^{t}\boldsymbol{\cdot }\tilde{\boldsymbol{f}}\hspace{2.22198pt}R_{C}\,\text{d}Z_{C}\,\text{d}R_{C}\\ \displaystyle +\int _{0}^{\infty }\int _{\unicode[STIX]{x1D705}}^{1-s}\tilde{\boldsymbol{u}}^{t}\boldsymbol{\cdot }\tilde{\boldsymbol{f}}\hspace{2.22198pt}R_{C}\,\text{d}Z_{C}\,\text{d}R_{C}\end{array}\right\}\,\text{d}\unicode[STIX]{x1D703}_{C}.\end{eqnarray}$$

The integration in the above equation is carried out analytically in the $\unicode[STIX]{x1D703}_{C}$ , $R_{C}$ and $Z_{C}$ directions. The integration over the Fourier parameters is performed numerically using the Gauss–Kronrod quadrature built into Mathematica 11.0. The contribution from sub-region (i) is evaluated analytically (see appendix C) and incorporated in our results.

5 Summary of the procedure

Here we summarize the solution procedure followed in this work for the evaluation of inertial lift volume integral (2.36).

  1. (i) First, the electrostatic potential ( $\unicode[STIX]{x1D713}$ ) is evaluated using the method of reflections ( $\unicode[STIX]{x1D713}_{1}+\unicode[STIX]{x1D713}_{2}$ ) in § 3.1. $\unicode[STIX]{x1D713}_{1}$ is found in terms of spherical harmonics, whereas the second reflection is obtained via Faxén transformations (Faxén Reference Faxén1922).

  2. (ii) The velocity disturbance field is obtained using the method of reflections in § 3.2. The first reflection ( $\boldsymbol{v}_{1}^{(0)}$ ) is found using Lamb’s general solution (Lamb Reference Lamb1975). The second reflection is found using Faxén transformations. The third reflection is found by again making use of Lamb’s solution.

  3. (iii) The unknown translational ( $\boldsymbol{U}_{s}^{(0)}$ ) and rotational ( $\unicode[STIX]{x1D734}_{s}^{(0)}$ ) velocities are found by imposing force-free and torque-free conditions on the particle in § 3.3.

  4. (iv) The test field is evaluated in § A.5, following the methodology in (ii).

  5. (v) The evaluated fields are substituted into the inertial lift force integral (2.36).

In the following sections, we discuss the results for the inertial lift ( $F_{I}$ ) experienced by the particle.

6 Inertial migration of an inert particle

The inertial migration of a neutrally buoyant inert particle is discussed in this section. We consider pure hydrodynamic flows (such as Couette and Poiseuille flow) and understand the mechanisms which contribute to the lift by using an order-of-magnitude analysis.

6.1 Validation with earlier theoretical studies

We first compare the results obtained in our work with those in the literature (Ho & Leal Reference Ho and Leal1974; Vasseur & Cox Reference Vasseur and Cox1976). Figure 3(a) shows the lift force experienced by a neutrally buoyant sphere freely suspended in Couette flow. There exists a single equilibrium position at the centre where the particle experiences no lift. Below the centreline ( $s<0.5$ ) the force acting on the particle is positive, resulting in a lift in the positive $z$ -direction (i.e. towards the centreline). Above the centreline ( $s>0.5$ ) the lift force is in the negative $z$ -direction (i.e. again towards the centreline). Hence, a neutrally buoyant particle in a Couette flow always migrates to the centre of the channel (a stable equilibrium) as depicted by the arrows on the axis.

For Poiseuille flow (figure 3 b), three equilibrium positions ‘a’, ‘b’ and ‘c’ exist ( $s\approx 0.19$ , 0.5 and 0.81). Points ‘a’ and ‘c’ are characterized by a negative slope of the lift force curve and are therefore stable equilibrium positions, while point ‘b’ is unstable (arrows on the axis depict the direction of migration).

Our results (for both Couette and Poiseuille flow) obtained by using Ho and Leal’s formulation are in good agreement with Vasseur & Cox (Reference Vasseur and Cox1976) who used a Green’s function technique to approximate the particle as a point force. Near the walls, lift force deviates significantly from Ho & Leal (Reference Ho and Leal1974). This may have been due to a failure in their numerical convergence near the walls, as pointed out by Vasseur & Cox (Reference Vasseur and Cox1976).

Figure 3. Comparison with the previous theoretical studies (Ho & Leal Reference Ho and Leal1974; Vasseur & Cox Reference Vasseur and Cox1976) for the inertial lift force experienced by a particle, as a function of distance from the bottom wall for: (a) Couette flow and (b) Poiseuille flow.

6.2 Insights into the origins of the inertial lift

The approach adopted in this work allows us to find different contributions to the lift force on a particle suspended in a Poiseuille flow. These constituents are interpreted using an order-of-magnitude analysis.

In the outer coordinates, the order of magnitude of background velocity is

(6.1) $$\begin{eqnarray}\tilde{\boldsymbol{V}}_{\infty }^{(0)}\sim O(1/\unicode[STIX]{x1D705})\unicode[STIX]{x1D6FD}+O(1/\unicode[STIX]{x1D705}^{2})\unicode[STIX]{x1D6FE}+O(1)\unicode[STIX]{x1D6FE},\end{eqnarray}$$

the disturbance velocity (stresslet) is

(6.2) $$\begin{eqnarray}\tilde{\boldsymbol{v}}^{(0)}\sim O(\unicode[STIX]{x1D705}^{2})\unicode[STIX]{x1D6FD}(1+W_{D}),\end{eqnarray}$$

and the test velocity field is

(6.3) $$\begin{eqnarray}\tilde{\boldsymbol{u}}^{t}\sim O(\unicode[STIX]{x1D705})(1+W_{A}^{t}).\end{eqnarray}$$

Here, $W_{D}$ and $W_{A}^{t}$ are the wall correction factors for stresslet and Stokeslet (test field) disturbances, respectively.

Upon substitution of (6.1)–(6.3) into the lift force expression (4.12), we obtain

(6.4) $$\begin{eqnarray}O\left(\frac{F_{I}}{Re_{p}}\right)\sim \int _{V_{f}}[O(1)\unicode[STIX]{x1D6FD}\unicode[STIX]{x1D6FD}(1+W_{D})+O(1/\unicode[STIX]{x1D705})\unicode[STIX]{x1D6FE}\unicode[STIX]{x1D6FD}(1+W_{D})]\,\text{d}\tilde{V}.\end{eqnarray}$$

The first term in the above equation is the stresslet-wall force (known in the literature as the ‘wall lift’ force). It originates from the interaction of the stresslet disturbance with the wall. This results in a pressure asymmetry around the particle. The pressure is larger on the side facing the closer wall (Feng et al. Reference Feng, Hu and Joseph1994). This force always acts away from the wall, even if the shear direction (the sign of $\unicode[STIX]{x1D6FD}$ ) is reversed, as it is proportional to $\unicode[STIX]{x1D6FD}^{2}$ . The second term is the stresslet-curvature force (known in the literature as the ‘shear-gradient lift force’), arising from the interaction of the stresslet disturbance ( $\unicode[STIX]{x1D6FD}(1+W_{D})$ ) with curvature in the background flow $(\unicode[STIX]{x1D6FE})$ . Owing to the proportionality to $\unicode[STIX]{x1D6FD}\unicode[STIX]{x1D6FE}$ , this force always acts towards the walls.

Figure 4. Variation of leading constituents of inertial lift force as a function of distance from the bottom wall for Poiseuille flow. Here, stresslet-wall force (SWF) is the ‘wall lift force’ and stresslet-curvature force (SCF) is the ‘shear-gradient lift force’.

Figure 4 shows the variation of the above two components with the lateral position. The stresslet-wall force (SWF) acts to push the particle towards the centreline. Since SWF depends on the background shear ( $\unicode[STIX]{x1D6FD}^{2}$ ), it vanishes at the centre and increases near the walls. On the other hand, the stresslet-curvature force (SCF) has a destabilizing effect at the centreline i.e. a slight perturbation to the particle would push it away from the centre. SCF increases (in magnitude) away from the centreline, and decreases near the stationary walls due to increased viscous resistance.

From (6.4) it can be observed that the direction of SCF is proportional to $\text{sgn}(\unicode[STIX]{x1D6FD}\unicode[STIX]{x1D6FE})$ . If either the shear or the curvature direction is changed, the direction of SCF can reverse. This can be exploited to control the positions at which the particle gets focused. Lee et al. (Reference Lee, Nam, Kim, Di Carlo and Lee2018) recently showed that the curvature of the background flow profile can be controlled by using stratified flows with different viscosities. By varying the viscosity ratio, an external control over the focusing position was experimentally demonstrated.

7 Electrophoresis combined inertial lift

We now focus on the effect that electrophoresis has on the inertial lift. This effect is captured in the absence of walls by the analytical expression derived in § 4.1 (see (4.7)). Here, we discuss the results which incorporate the wall effects to first order. In figure 5(a), the variation of the lift force with position is shown for three different systems in which the electric field is applied in the same direction as the flow. A particle with $Z_{p}=0$ corresponds to an inert particle and has three equilibrium positions as discussed in § 6.1. A particle with $(Z_{p}>0)$ , leads the background flow, and the stable equilibrium position shifts towards the walls. For a particle with $Z_{p}<0$ , the stable equilibrium positions shift inwards towards the centre. This shift in equilibrium positions based on zeta potential is predicted by (4.7). These trends are consistent with those observed in the experiments performed by Kim & Yoo (Reference Kim and Yoo2009a ,Reference Kim and Yoo b ), Cevheri & Yoda (Reference Cevheri and Yoda2014), Yuan et al. (Reference Yuan, Pan, Zhang, Yan, Zhao, Alici and Li2016), Li & Xuan (Reference Li and Xuan2018) and Yee & Yoda (Reference Yee and Yoda2018).

It is of interest to determine the underlying interactions which cause the shift in the equilibrium positions. When a rigid particle is suspended in shear flow, it gives rise to a stresslet disturbance. Upon the application of an external electric field, an additional source-dipole disturbance emerges due to the electrokinetic slip. These disturbance fields (stresslet and slip-originated source dipole) upon mutual interaction among themselves; upon interaction with the background flow (shear $\unicode[STIX]{x1D6FD}$ and curvature $\unicode[STIX]{x1D6FE}$ ) and walls, contribute to the electrophoresis combined inertial lift. To interpret the underlying mechanisms which cause the shift in migration, we dissect the forces into various constituents via an order-of-magnitude analysis. We then evaluate and explain these constituents separately (as in § 6.2).

Figure 5. Variation of the inertial lift force on the electrophoretic particle with distance from the bottom wall: (a) effect of zeta potential for $Ha=1.25$ ( $E_{\infty }^{\prime }=70~\text{V}~\text{cm}^{-1}$ ); (b) comparison of the phoretic lift with SCF (stresslet-curvature force) and SWF (stresslet-wall force) for $Z_{p}=0.67$ . The dashed line shows the analytical expression, expressed in (4.7) (which does not account for the wall effects). Parameters: $\unicode[STIX]{x1D701}_{p}^{\prime }=47~\text{mV}$ , $U_{max}^{\prime }=2.25~\text{mm}~\text{s}^{-1}$ , $a^{\prime }=10~\unicode[STIX]{x03BC}\text{m}$ , $l^{\prime }=1~\text{mm}$ , $\unicode[STIX]{x1D700}^{\prime }=80\unicode[STIX]{x1D700}_{0}^{\prime }$ , $\unicode[STIX]{x1D707}^{\prime }=10^{-3}~\text{Pa}~\text{s}$ .

The order of background velocity in terms of outer coordinates is given by

(7.1) $$\begin{eqnarray}\tilde{\boldsymbol{V}}_{\infty }^{(0)}\sim O(1/\unicode[STIX]{x1D705})\unicode[STIX]{x1D6FD}+O(1/\unicode[STIX]{x1D705}^{2})\unicode[STIX]{x1D6FE}+O(1)\unicode[STIX]{x1D6FE}+O(1)\,HaZ_{p},\end{eqnarray}$$

the order of disturbance velocity (stresslet and source-dipole) field is

(7.2) $$\begin{eqnarray}\tilde{\boldsymbol{v}}^{(0)}\sim O(\unicode[STIX]{x1D705}^{2})\unicode[STIX]{x1D6FD}(1+W_{D})+O(\unicode[STIX]{x1D705}^{3})HaZ_{p}(1+W_{B}),\end{eqnarray}$$

and the order of test velocity field is

(7.3) $$\begin{eqnarray}\tilde{\boldsymbol{u}}^{t}\sim O(\unicode[STIX]{x1D705})(1+W_{A}^{t}).\end{eqnarray}$$

Substituting the above expressions in the lift force (4.12), we obtain seven components which contribute to the inertial force experienced by an electrophoretic particle. These arise from various interactions in the system (see table 2). The first two components (SWF and SCF) belong to the lift associated with an inert particle suspended in Poiseuille flow and were discussed in § 6.2. The remaining five components (table 2: nos. 3–7), arising from the introduction of electrophoresis, can be lumped into what we term as ‘phoretic lift’ (as this lift is general for any phoretic transport such as thermophoresis or diffusiophoresis). Figure 5(b) compares the phoretic lift on a positive $Z_{p}$ particle with the stresslet-wall force (SWF) and stresslet-curvature force (SCF). A positive slope at the centreline depicts that the phoretic lift acts in the direction of SCF and contributes to pushing the leading particle towards the walls. This results in an outward shift of equilibrium positions i.e. a leading particle finds equilibrium nearer to the walls.

The analytical expression derived in § 4.1 $(-47\unicode[STIX]{x03C0}\unicode[STIX]{x1D6FD}HaZ_{p}Re_{p}/20)$ is plotted as a dashed line in figure 5(b). Since it is proportional to the background shear, the trend remains linear throughout the channel width. It can also be seen from figure 5(b) that the phoretic lift (which incorporates the wall correction) agrees with the analytical expression away from the walls. The increased viscous resistance near the walls reduces the phoretic lift, and causes a deviation from the linear analytical expression. The effect of wall on the phoretic lift is weak because it is short-ranged, as it is caused by rapidly decaying source-dipole field ( $O(1/r^{3})$ ). On the other hand, the stresslet-wall force (SWF) and stresslet-curvature force (SCF) are characterized by a less rapidly decaying stresslet field ( $O(1/r^{2})$ ). Therefore, SWF and SCF are influenced sufficiently far away from the walls.

Table 2. Components which constitute the electrophoresis combined inertial lift force. The forces arising due to electrophoresis are subscripted by ‘E’ because the external agency is electric field. The first two components are the same as described in figure 4.

The phoretic lift force is composed of five components listed in table 2 (nos. 3–7). Figure 6 illustrates their variation with respect to lateral position. Major components which govern the phoretic lift are plotted in figure 6(a). The disturbance–disturbance interaction term $(\boldsymbol{v}^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}^{(0)})$ (no. 3 in table 2) contributes primarily to the phoretic lift. The proportionality to $\unicode[STIX]{x1D6FD}HaZ_{p}$ suggests that this must arise from the interaction between stresslet and source-dipole disturbance, and is therefore classified as stresslet-phoretic force (SPF $_{\text{E}}$ ). This SPF $_{\text{E}}$ acts to push the leading particle towards the walls. These interactions are short ranged, and therefore the associated force decays (due to viscous resistance) only when the particle is close to the walls. The other two significant forces arise from the interaction of disturbance field and the background flow ( $(\boldsymbol{V}_{\infty }^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{v}^{(0)})$ and $(\boldsymbol{v}^{(0)}\boldsymbol{\cdot }\unicode[STIX]{x1D735}\boldsymbol{V}_{\infty }^{(0)})$ ). The interaction of phoretic disturbance with the background shear results in a phoretic-shear force (PSF $_{\text{E}}$ ). A stresslet-lead/lag force (SLF $_{\text{E}}$ ) occurs when the quadrupolar symmetry of pressure around the particle (characteristic of stresslet disturbance) is distorted due to an externally imposed lead/lag. From figure 6(a) we conclude that when a particle leads the flow (i.e. $HaZ_{p}>0$ ), all the three components: SPF $_{\text{E}}$ , PSF $_{\text{E}}$ , and SLF $_{\text{E}}$ push it towards the walls, while the reverse is true for a lagging particle.

Other minor components of the phoretic lift are shown in figure 6(b) (compare the $y$ -axis scale). Contrary to the background shear, the curvature interacts with the source-dipole disturbance to produce lift (phoretic-curvature force) in the opposite direction but at a much lower magnitude. The phoretic-wall force (PWF $_{\text{E}}$ ) occurs due to the interaction of rapidly decaying phoretic disturbance with the walls (analogous to stresslet-wall force). This weak PWF $_{\text{E}}$ would exist in isolation for inertial migration in a pure electrokinetic flow (i.e. absence of external pressure drop). Moreover, PWF $_{\text{E}}$ always acts towards the centreline irrespective of the sign of the electric field or zeta potential, as it is proportional to $(HaZ_{p})^{2}$ .

From the results, we observe that, in Poiseuille flow, the effect of electrophoresis on the inertial migration (phoretic-lift) is qualitatively similar to that of a non-neutrally buoyant particle (Saffman Reference Saffman1965) i.e. a particle leading the flow, migrates towards the region of high shear and vice versa for a lagging particle. Therefore, it is of interest to find the fundamental differences between the two systems. Towards this, in the next section, we investigate the influence of a force-driven phenomenon (buoyancy) on the inertial migration. We then differentiate it from the slip-driven phenomenon (electrophoresis) in terms of its influence on the inertial migration.

Figure 6. Variation of (a) major and (b) minor components of the phoretic lift, for a leading particle. See table 2 for the details of abbreviations. Parameters: $\unicode[STIX]{x1D701}_{p}^{\prime }=47~\text{mV}$ , $U_{max}^{\prime }=2.25~\text{mm}~\text{s}^{-1}$ , $a^{\prime }=10~\unicode[STIX]{x03BC}\text{m}$ , $l^{\prime }=1~\text{mm}$ , $\unicode[STIX]{x1D700}^{\prime }=80\unicode[STIX]{x1D700}_{0}^{\prime }$ , $\unicode[STIX]{x1D707}^{\prime }=10^{-3}~\text{Pa}~\text{s}$ , $E_{\infty }^{\prime }=70~\text{V}~\text{cm}^{-1}$ .

8 Comparisons with buoyancy combined inertial lift

In the previous section, we analysed the influence on the inertial lift due to an external field, which makes the particle lag or lead the flow via a ‘force-free mechanism’. We now focus our attention on the inertial lift experienced by a non-neutrally buoyant inert particle suspended in a Poiseuille flow. The gravitational field acts parallel to the flow and makes the particle lag/lead via a ‘forced mechanism’. The associated disturbance profile is fundamentally different from the force-free scenario (see figure 1). Therefore, we focus on the influence of these differences on particle migration.

Following the procedure described in § 3, the translational and rotational velocities are found by balancing the hydrodynamic drag with buoyancy and rendering the particle torque-free. This results in

(8.1) $$\begin{eqnarray}\displaystyle & \displaystyle U_{s\,x}^{(0)}\approx \frac{(\unicode[STIX]{x1D6FC}+\unicode[STIX]{x1D6FE}/3)(1+\unicode[STIX]{x1D705}W_{A})-10\unicode[STIX]{x1D705}^{2}\unicode[STIX]{x1D6FD}W_{D}/9+{\mathcal{B}}}{(1+\unicode[STIX]{x1D705}W_{A})}, & \displaystyle\end{eqnarray}$$
(8.2) $$\begin{eqnarray}\displaystyle & \displaystyle \unicode[STIX]{x1D6FA}_{s\,y}^{(0)}\approx \frac{\unicode[STIX]{x1D6FD}(1+\unicode[STIX]{x1D705}W_{A})-(10{\mathcal{X}}_{D}\unicode[STIX]{x1D705}^{3}\unicode[STIX]{x1D6FD}/3)+3{\mathcal{B}}{\mathcal{X}}_{A}\unicode[STIX]{x1D705}^{2}}{2(1+\unicode[STIX]{x1D705}W_{A})}. & \displaystyle\end{eqnarray}$$

Here, ${\mathcal{B}}$ is the buoyancy number defined as the ratio of buoyancy to viscous drag force

(8.3) $$\begin{eqnarray}{\mathcal{B}}=\frac{\unicode[STIX]{x0394}\unicode[STIX]{x1D70C}^{\prime }(4\unicode[STIX]{x03C0}a^{\prime 3}/3)g^{\prime }}{6\unicode[STIX]{x03C0}\unicode[STIX]{x1D707}^{\prime }a^{\prime }U_{max}^{\prime }\unicode[STIX]{x1D705}}.\end{eqnarray}$$

Here, $\unicode[STIX]{x0394}\unicode[STIX]{x1D70C}^{\prime }$ is the density difference between the particle and fluid medium and $g^{\prime }$ is the acceleration due to gravity.

In § 7, we analysed the effect of electrophoresis on the inertial migration for $HaZ_{p}\sim O(1)$ . The corresponding electrophoretic velocity was of the order of the characteristic velocity i.e. $O(\boldsymbol{U}_{E}^{\prime })\sim O(\unicode[STIX]{x1D705}U_{max}^{\prime })$ . For an equitable comparison, we choose the buoyancy number ( ${\mathcal{B}}$ ) to be such that the lag/lead produced by the density difference is of the same order as that in the electrophoretic system; ${\mathcal{B}}\sim O(1)$ corresponds to the settling velocity of the sphere being of the order of the characteristic velocity ( $U_{set}^{\prime }\sim \unicode[STIX]{x1D705}U_{max}^{\prime }$ ). Here $U_{set}^{\prime }$ is the settling velocity corresponding to ${\mathcal{B}}$ . Figure 7 depicts the lift force corresponding to ${\mathcal{B}}=1$ . The curve shows that, for the flow aligned in the direction of gravity, a heavy particle ( ${\mathcal{B}}>0$ ) migrates towards the walls. Our result agrees well with that of Vasseur & Cox (Reference Vasseur and Cox1976) who addressed a similar regime of buoyancy: $\unicode[STIX]{x1D705}^{2}U_{max}^{\prime }\ll U_{set}^{\prime }\ll U_{max}^{\prime }$ . A slight mismatch arises near the walls because their analysis assumes that the particle settles with a constant velocity for all ‘ $s$ ’ while we take wall resistance into account which reduces the settling velocity significantly near the walls.

Figure 7. Lift force on a non-neutrally buoyant particle in a Poiseuille flow and comparison with Vasseur & Cox (Reference Vasseur and Cox1976). Parameters: $a^{\prime }=10~\unicode[STIX]{x03BC}\text{m}$ , $l^{\prime }=1~\text{mm}$ , $U_{max}^{\prime }=2.25~\text{mm}~\text{s}^{-1}$ , $\unicode[STIX]{x1D707}^{\prime }=10^{-3}~\text{Pa}~\text{s}$ and $\unicode[STIX]{x0394}\unicode[STIX]{x1D70C}^{\prime }=100~\text{kg}~\text{m}^{-3}$ .

Table 3. Lift force components which comprise the additional lift force occurring due to a non-neutrally buoyant particle. The subscript ‘G’ denotes that the forces arise from an external gravitational field.

Figure 8. Variation of (a) major components (SSF $_{\text{G}}$ and SCF $_{\text{G}}$ ) and (b) minor components (SWF $_{\text{G}}$ and SLF $_{\text{G}}$ ) of buoyancy combined inertial force as a function of distance from the bottom wall (see table 3). Parameters: $a^{\prime }=10~\unicode[STIX]{x03BC}\text{m}$ , $l^{\prime }=1~\text{mm}$ , $U_{max}^{\prime }=2.25~\text{mm}~\text{s}^{-1}$ , $\unicode[STIX]{x1D707}^{\prime }=10^{-3}~\text{Pa}~\text{s}$ and $\unicode[STIX]{x0394}\unicode[STIX]{x1D70C}^{\prime }=100~\text{kg}~\text{m}^{-3}$ .

As in § 7, we analyse the order-of-magnitude of various components of the inertial lift for a non-neutrally buoyant particle. We obtain four additional components apart from stresslet-wall force (SWF) and stresslet-curvature force SCF (see § 6.2). Table 3 illustrates these additional components of buoyancy combined with inertial lift, which arise from the various interactions. Contrary to the electrophoretic case, the contribution emerging due to the disturbance–disturbance interactions is found to be negligible in this case and hence are not discussed here. We also find that the expressions for the components contributing to the lift, emerging due to buoyancy (table 3, nos. 1–4), are analogous to those arising from electrophoresis (cf. table 2, nos. 4–7). Furthermore, the components of the two cases show similar effects on migration. For instance, both phoretic-shear force and Stokeslet-shear force direct the leading particle to focus at walls, while phoretic-curvature and Stokeslet-curvature forces direct the leading particle towards the centre.

In figure 8(a), we show that Stokeslet-shear (SSF $_{\text{G}}$ ) and Stokeslet-curvature forces (SCF $_{\text{G}}$ ) dominate over the SWF and SCF (emerging from stresslet, discussed in § 6.2): SSF $_{\text{G}}$ and SCF $_{\text{G}}$ primarily govern the migration for a non-neutrally buoyant particle; unlike the electrophoretic case where the phoretic lift was found to be comparable to SWF and SCF (see figure 5 b). We conclude, on the basis of equitable lead/lag, that the modification to inertial lift arising due to density difference is much greater than that caused due to electrophoresis. Furthermore, we observe that the components involving interaction with the background curvature (PCF $_{\text{E}}$ and SCF $_{\text{G}}$ ), oppose the interactions involving the background shear (PSF $_{\text{E}}$ and SSF $_{\text{G}}$ ), irrespective of the external driving mechanism (such as gravity or electric field).

If the ratio of settling velocity to the background flow is asymptotically large (i.e. $U_{set}^{\prime }\gg U_{max}^{\prime }$ ), only the Stokeslet-wall force (SWF $_{\text{G}}$ ) exists. This corresponds to a sedimentation of a particle in a quiescent fluid ( $\unicode[STIX]{x1D6FD}\equiv 0$ and $\unicode[STIX]{x1D6FE}\equiv 0$ ). The particle would focus at the centreline for both positive and negative density differences (as SWF $_{\text{G}}$ is proportional to ${\mathcal{B}}^{2}$ ). In figure 8(b), we find that the SWF $_{\text{G}}$ matches well with the inertial lift reported by Vasseur & Cox (Reference Vasseur and Cox1976) for a sedimenting particle (in quiescent fluid). The deviation near the walls is attributed to the inclusion of first-order wall correction in our approach (see (8.1)). Whereas Vasseur & Cox (Reference Vasseur and Cox1976) assumed a constant settling velocity irrespective of the particle position between the walls.

9 Comparisons with the decoupled electric lift

In § 3.1, we showed that the electrical force $\boldsymbol{F}_{M}$ (arising from the Maxwell stresses) contributes to the lateral migration of the particle (see (3.8)). This force pushes the particle away from the walls, irrespective of the particle zeta potential. On the other hand, the inertial lift on an electrophoretic particle depends on the zeta potential (see figure 5 a). Therefore, the equilibrium positions of an electrophoretic particle will be determined by the relative magnitudes of the electric lift (EL) and the electrophoresis combined inertial lift (EIL). Here we compare the contributions arising from these two effects.

In figure 9(a), we show the variation of the two lifts with lateral position between the walls, where the electric field is applied in the direction of the flow ( $Ha>0$ ). For $\unicode[STIX]{x1D705}\ll 1$ , we find that the wall-repulsive EL decays rapidly away from the wall and becomes negligible in the bulk of the channel. The migration of an electrophoretic particle is therefore determined by EIL in the bulk of the channel.

Figure 9(b) shows the variation of equilibrium positions ( $s_{eq}$ ) with the strength of the applied electric field ( $Ha$ ). Here, the equilibrium positions are determined by the total lateral lift on the particle (i.e. EL $+$ EIL). The solid lines depict stable equilibrium positions, whereas the dashed line represents an unstable equilibrium. The curves resemble a classic supercritical pitchfork bifurcation (Strogatz Reference Strogatz2018). As we increase the electric field strength in the negative $x$ -direction, for a fixed zeta potential ( $\unicode[STIX]{x1D701}_{p}^{\prime }=+47~\text{mV}$ ) and particle to channel size ratio ( $\unicode[STIX]{x1D705}=0.01$ ), a critical $Ha$ exists ( ${\approx}-\!1.8$ ), below which the particle focuses only at the centreline. At this point, the centre equilibrium point undergoes a transition from an unstable to stable equilibrium because the phoretic lift is sufficiently strong to overcome the stresslet-curvature force (SCF).

Figure 9. (a) Comparison of electrophoresis combined inertial lift (EIL) with the electric lift (EL) (3.8) for $\unicode[STIX]{x1D701}_{p}^{\prime }=47~\text{mV}$ and $\unicode[STIX]{x1D701}_{p}^{\prime }=-47~\text{mV}$ . Parameters: $Ha=+1.25$ ; $E_{\infty }^{\prime }=70~\text{V}~\text{cm}^{-1}$ , $U_{max}^{\prime }=2.25~\text{mm}~\text{s}^{-1}$ , $a^{\prime }=10~\unicode[STIX]{x03BC}\text{m}$ , $l^{\prime }=1~\text{mm}$ , $\unicode[STIX]{x1D700}^{\prime }=80\unicode[STIX]{x1D700}_{0}^{\prime }$ , $\unicode[STIX]{x1D707}^{\prime }=10^{-3}~\text{Pa}~\text{s}$ , $\unicode[STIX]{x1D70C}^{\prime }=10^{3}~\text{kg}~\text{m}^{-3}$ . (b) Effect of $Ha$ and size ratio ( $\unicode[STIX]{x1D705}=0.01$ and $\unicode[STIX]{x1D705}=0.02$ ) on the equilibrium positions ( $\unicode[STIX]{x1D701}_{p}^{\prime }=47~\text{mV}$ ). A negative $Ha$ implies that the electric field and the flow are in the opposite directions.

As the electric field strength is increased in the positive $x$ -direction, the equilibrium positions shift towards the walls. We can also observe from figure 9(b) that a strong electric lift prevents the particle from focusing near the walls. This effect is prominent for a larger particle ( $\unicode[STIX]{x1D705}=0.02$ ). The analysis in this section helps establish that the separation of particles can be carried out based on size, surface charge and external electric field.

10 Conclusions

Motivated by recent experimental observations (Kim & Yoo Reference Kim and Yoo2009a ; Cevheri & Yoda Reference Cevheri and Yoda2014; Yuan et al. Reference Yuan, Pan, Zhang, Yan, Zhao, Alici and Li2016; Li & Xuan Reference Li and Xuan2018), we analyse the inertial lift on an electrophoretic particle suspended in a combined electro-osmotic Poiseuille flow by using the framework of Ho & Leal (Reference Ho and Leal1974). We use the reciprocal theorem in conjunction with perturbation expansion (in particle Reynolds number) to obtain the lift arising from weak inertia. The Stokes velocity fields are found by using the method of reflections; odd reflections are obtained using Lamb’s solution (Lamb Reference Lamb1975) and even reflections are obtained using Faxén transform (Faxén Reference Faxén1922). By neglecting the wall effects, we obtain an analytical expression for the ‘phoretic lift’ which captures the influence of electrophoresis on inertial migration. Later we include the wall effects at the leading order. We find that our results agree qualitatively with the experimental observations; a leading particle migrates towards the regions of low background velocity (i.e. walls) while the reverse occurs for a lagging particle.

The chosen framework allows us to perform an order-of-magnitude analysis and obtain various components which contribute to the inertial lift. We classify these components on the basis of the interactions which cause them. Our results reveal that the phoretic lift arises primarily due to short-ranged interactions between electrokinetic slip-driven source-dipole field and the stresslet field (generated due to particle resistance to strain in the background Poiseuille flow). We observe that, the effect of electrophoresis on the inertial migration (phoretic lift) is qualitatively similar to that of non-neutrally buoyant particle (Saffman Reference Saffman1965). Therefore, to differentiate the slip-driven phenomenon (electrophoresis) from a force-driven phenomenon (buoyancy) in terms of their influence on the inertial migration, we further study the migration of a non-neutrally buoyant particle in Poiseuille flow. The buoyancy-driven motion of the particle generates a Stokeslet field at the leading order. We find that the interaction of this field with the background shear primarily influences the inertial migration. Contrary to electrophoresis, this interaction is long-ranged and the corresponding lift is much stronger than the phoretic lift.

Finally, we show that the particles can be focused near the centre (or at the walls) if a sufficiently high electric field is applied in a suitable direction. A decoupled wall-repulsive electric lift (derived in this work as an extension to Yariv (Reference Yariv2006)) may prevent the particle from focusing near the walls and hinder the particle separation. For asymptotically small particles ( $\unicode[STIX]{x1D705}\ll 1$ ), this electric lift decays sharply away from the walls, and does not affect the equilibrium positions in the bulk of the channel.

Although this work is limited to weak inertia, we believe that these findings provide a first step towards understanding the influence of electric fields on inertial migration of particles, which provides a good starting point for further research. For instance, the problem becomes challenging for higher Reynolds numbers as the streaming potential (arising from the convection of ions in the double layer) might contribute significantly to the inertial lift (Schnitzer, Frankel & Yariv Reference Schnitzer, Frankel and Yariv2012b ). Furthermore, for high particle zeta potentials, surface conduction effects might significantly alter the electrokinetic slip and cause substantial deviation from the inertial lift. These questions may constitute the objective for future studies.

Acknowledgements

First author A.C. is indebted to Dr A. Roy of the Applied Mechanics Department at Indian Institute of Technology Madras for his lectures on microhydrodynamics and fruitful discussions. The authors are also thankful to Dr S. Thampi of the Chemical Engineering Department at Indian Institute of Technology Madras for his feedback. A.C. is also grateful to MHRD, Govt. of India, for financial support.

Supplementary material

Supplementary material is available at https://doi.org/10.1017/jfm.2019.479.

Appendix A.

A.1 Justification of neglect of translational and angular acceleration

In this appendix, we justify the force-free and torque-free assumption in (2.24) and (2.25). We choose the time scale to be $t_{conv}^{\prime }$ , and obtain the dimensionless force and torque balance as

(A 1) $$\begin{eqnarray}\left.\begin{array}{@{}c@{}}\boldsymbol{F}=\displaystyle \int _{S_{p}}\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{H}\,\text{d}S+4\unicode[STIX]{x03C0}Ha\int _{S_{p}}\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{M}\,\text{d}S={\displaystyle \frac{4\unicode[STIX]{x03C0}}{3}}Re_{p}{\displaystyle \frac{\unicode[STIX]{x2202}\boldsymbol{U}_{s}}{\unicode[STIX]{x2202}t}},\\ \boldsymbol{L}=\displaystyle \int _{S_{p}}\boldsymbol{n}\times (\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{H})\,\text{d}S+4\unicode[STIX]{x03C0}Ha\int _{S_{p}}\boldsymbol{n}\times (\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{M})\,\text{d}S={\displaystyle \frac{4\unicode[STIX]{x03C0}}{3}}Re_{p}{\displaystyle \frac{\unicode[STIX]{x2202}\unicode[STIX]{x1D734}_{s}}{\unicode[STIX]{x2202}t}}.\end{array}\right\}\end{eqnarray}$$

The substitution of perturbation expansion (2.27) in the above equation provides us the force balance at $O(1)$

(A 2) $$\begin{eqnarray}\left.\begin{array}{@{}c@{}}\boldsymbol{F}^{(0)}=\displaystyle \int _{S_{p}}\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{H}^{(0)}\,\text{d}S+4\unicode[STIX]{x03C0}Ha\int _{S_{p}}\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{M}\,\text{d}S=\mathbf{0},\\ \boldsymbol{L}^{(0)}=\displaystyle \int _{S_{p}}\boldsymbol{n}\times (\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{H}^{(0)})\,\text{d}S+4\unicode[STIX]{x03C0}Ha\int _{S_{p}}\boldsymbol{n}\times (\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{M})\,\text{d}S=\mathbf{0},\end{array}\right\}\end{eqnarray}$$

and at $O(Re_{p})$

(A 3) $$\begin{eqnarray}\left.\begin{array}{@{}c@{}}\boldsymbol{F}^{(1)}=\displaystyle \int _{S_{p}}\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{H}^{(1)}\,\text{d}S={\displaystyle \frac{4\unicode[STIX]{x03C0}}{3}}{\displaystyle \frac{\unicode[STIX]{x2202}\boldsymbol{U}_{s}^{(0)}}{\unicode[STIX]{x2202}t}}=\mathbf{0},\\ \boldsymbol{L}^{(1)}=\displaystyle \int _{S_{p}}\boldsymbol{n}\times (\boldsymbol{n}\boldsymbol{\cdot }\unicode[STIX]{x1D748}_{H}^{(1)})\,\text{d}S={\displaystyle \frac{4\unicode[STIX]{x03C0}}{3}}{\displaystyle \frac{\unicode[STIX]{x2202}\unicode[STIX]{x1D734}_{s}^{(0)}}{\unicode[STIX]{x2202}t}}=\mathbf{0}.\end{array}\right\}\end{eqnarray}$$

Since $\boldsymbol{U}_{s}^{(0)}$ and $\unicode[STIX]{x1D734}_{s}^{(0)}$ are constant, the problems at $O(1)$ and $O(Re_{p})$ are force-free and torque-free. The translational and angular acceleration of the particle only affect the system at $O(Re_{p}^{2})$ .

A.2 Illustration of Faxén transformation

Since $\unicode[STIX]{x1D713}_{2}$ depends on $\unicode[STIX]{x1D713}_{1}$ through the wall boundary condition in (3.3), both reflections must be represented in the coordinates of same scale. The first reflection of potential disturbance in the outer coordinates ( $\tilde{\unicode[STIX]{x1D713}_{1}}$ ) is

(A 4) $$\begin{eqnarray}\tilde{\unicode[STIX]{x1D713}}_{1}=-\frac{1}{2}\frac{X}{R^{3}}\unicode[STIX]{x1D705}^{2}.\end{eqnarray}$$

Faxén (Reference Faxén1922) represented the fundamental solution of Laplace’s equation (in Cartesian space) in the form of Fourier integrals. Following Faxén, we write

(A 5) $$\begin{eqnarray}\frac{1}{R}=\frac{1}{2\unicode[STIX]{x03C0}}\int _{-\infty }^{+\infty }\int _{-\infty }^{+\infty }\text{e}^{(\text{i}\unicode[STIX]{x1D6E9}-(\unicode[STIX]{x1D706}|Z|/2))}\frac{\text{d}\unicode[STIX]{x1D709}\,\text{d}\unicode[STIX]{x1D702}}{2\unicode[STIX]{x1D706}},\end{eqnarray}$$

and

(A 6) $$\begin{eqnarray}R=\frac{1}{2\unicode[STIX]{x03C0}}\int _{-\infty }^{+\infty }\int _{-\infty }^{+\infty }(1-\text{e}^{(\text{i}\unicode[STIX]{x1D6E9}-(\unicode[STIX]{x1D706}|Z|/2))})\left(1+\frac{\unicode[STIX]{x1D706}|Z|}{2}\right)\frac{\text{d}\unicode[STIX]{x1D709}\,\text{d}\unicode[STIX]{x1D702}}{\unicode[STIX]{x1D706}^{3}/2}.\end{eqnarray}$$

Here, $\unicode[STIX]{x1D6E9}=(\unicode[STIX]{x1D709}X+\unicode[STIX]{x1D702}Y)/2$ and $\unicode[STIX]{x1D706}=(\unicode[STIX]{x1D709}^{2}+\unicode[STIX]{x1D702}^{2})^{1/2}$ . $\unicode[STIX]{x1D709}$ and $\unicode[STIX]{x1D702}$ are the variables in Fourier space. Using (A 5) and (A 6), we transform the disturbance field (A 4) by taking derivatives of the above equations. For example: (A 4) contains $X/R^{3}$ , which is expressed using the above transformations as

(A 7) $$\begin{eqnarray}\frac{X}{R^{3}}=-\frac{\unicode[STIX]{x2202}}{\unicode[STIX]{x2202}X}\left(\frac{1}{R}\right)=\frac{1}{2\unicode[STIX]{x03C0}}\int _{-\infty }^{+\infty }\int _{-\infty }^{+\infty }\text{e}^{(\text{i}\unicode[STIX]{x1D6E9}-(\unicode[STIX]{x1D706}|Z|/2))}\left(-\frac{\text{i}\unicode[STIX]{x1D709}}{2}\right)\frac{\text{d}\unicode[STIX]{x1D709}\,\text{d}\unicode[STIX]{x1D702}}{2\unicode[STIX]{x1D706}}.\end{eqnarray}$$

This yields an integral representation for the first reflection

(A 8) $$\begin{eqnarray}\tilde{\unicode[STIX]{x1D713}}_{1}=\frac{\unicode[STIX]{x1D705}^{2}}{2\unicode[STIX]{x03C0}}\int _{-\infty }^{+\infty }\int _{-\infty }^{+\infty }\text{e}^{(\text{i}\unicode[STIX]{x1D6E9}-(\unicode[STIX]{x1D706}|Z|/2))}b_{1}\left(\frac{\text{i}\unicode[STIX]{x1D709}}{\unicode[STIX]{x1D706}}\right)\text{d}\unicode[STIX]{x1D709}\,\text{d}\unicode[STIX]{x1D702}.\end{eqnarray}$$

Here, $b_{1}=1/8$ . The boundary condition expressed in (3.3) suggests a form of solution for $\tilde{\unicode[STIX]{x1D713}_{2}}$ similar to the above equation

(A 9) $$\begin{eqnarray}\tilde{\unicode[STIX]{x1D713}}_{2}=\frac{\unicode[STIX]{x1D705}^{2}}{2\unicode[STIX]{x03C0}}\int _{-\infty }^{+\infty }\int _{-\infty }^{+\infty }\text{e}^{\text{i}\unicode[STIX]{x1D6E9}}(\text{e}^{(-\unicode[STIX]{x1D706}Z/2)}b_{2}+\text{e}^{(+\unicode[STIX]{x1D706}Z/2)}b_{3})\left(\frac{\text{i}\unicode[STIX]{x1D709}}{\unicode[STIX]{x1D706}}\right)\,\text{d}\unicode[STIX]{x1D709}\,\text{d}\unicode[STIX]{x1D702}.\end{eqnarray}$$

Substituting (A 8) and (A 9) in the boundary condition (3.3), yields $b_{2}$ and $b_{3}$ in terms of $b_{1}$

(A 10a,b ) $$\begin{eqnarray}b_{2}=\frac{b_{1}(1+\text{e}^{(1-s)\unicode[STIX]{x1D706}})}{-1+\text{e}^{\unicode[STIX]{x1D706}}},\quad b_{3}=\frac{b_{1}(1+\text{e}^{s\unicode[STIX]{x1D706}})}{-1+\text{e}^{\unicode[STIX]{x1D706}}}.\end{eqnarray}$$

A.3 Evaluation of Maxwell stress-induced force and torque

The electric force and torque are expressed as a function of the reflections as

(A 11) $$\begin{eqnarray}\boldsymbol{F}_{M}=4\unicode[STIX]{x03C0}Ha\int _{S_{p}}\boldsymbol{n}\boldsymbol{\cdot }\left(\begin{array}{@{}c@{}}\unicode[STIX]{x1D735}(\unicode[STIX]{x1D713}_{1}+\unicode[STIX]{x1D713}_{2})\unicode[STIX]{x1D735}(\unicode[STIX]{x1D713}_{1}+\unicode[STIX]{x1D713}_{2})\\ -\,{\textstyle \frac{1}{2}}(\unicode[STIX]{x1D735}(\unicode[STIX]{x1D713}_{1}+\unicode[STIX]{x1D713}_{2})\boldsymbol{\cdot }\unicode[STIX]{x1D735}(\unicode[STIX]{x1D713}_{1}+\unicode[STIX]{x1D713}_{2}))\unicode[STIX]{x1D644}\end{array}\right)\text{d}S,\end{eqnarray}$$
(A 12) $$\begin{eqnarray}\boldsymbol{L}_{M}=4\unicode[STIX]{x03C0}Ha\int _{S_{p}}\boldsymbol{n}\times \left(\boldsymbol{n}\boldsymbol{\cdot }\left(\begin{array}{@{}c@{}}\unicode[STIX]{x1D735}(\unicode[STIX]{x1D713}_{1}+\unicode[STIX]{x1D713}_{2})\unicode[STIX]{x1D735}(\unicode[STIX]{x1D713}_{1}+\unicode[STIX]{x1D713}_{2})\\ -\,{\textstyle \frac{1}{2}}(\unicode[STIX]{x1D735}(\unicode[STIX]{x1D713}_{1}+\unicode[STIX]{x1D713}_{2})\boldsymbol{\cdot }\unicode[STIX]{x1D735}(\unicode[STIX]{x1D713}_{1}+\unicode[STIX]{x1D713}_{2}))\unicode[STIX]{x1D644}\end{array}\right)\right)\text{d}S.\end{eqnarray}$$

The gradient of first reflection ( $\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}_{1}$ ) at the particle surface is

(A 13) $$\begin{eqnarray}\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}_{1}|_{r=1}={\textstyle \frac{1}{2}}\{-1+3\sin ^{2}\unicode[STIX]{x1D703}\cos ^{2}\unicode[STIX]{x1D711},3\sin ^{2}\unicode[STIX]{x1D703}\sin \unicode[STIX]{x1D711}\cos \unicode[STIX]{x1D711},3\sin \unicode[STIX]{x1D703}\cos \unicode[STIX]{x1D703}\cos \unicode[STIX]{x1D711}\}.\end{eqnarray}$$

Here, $\unicode[STIX]{x1D711}$ and $\unicode[STIX]{x1D703}$ denote the azimuthal and polar angle, respectively. Since the wall reflected potential ( $\tilde{\unicode[STIX]{x1D713}_{2}}$ ) has been expressed in the outer coordinates ( $R,X,Y,Z$ ) in (3.6), $\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}_{2}$ at the particle surface ( $r=1$ ) is expressed as a Taylor series expansion of $\unicode[STIX]{x1D705}\tilde{\unicode[STIX]{x1D735}}\tilde{\unicode[STIX]{x1D713}_{2}}$ about the origin ( $R\rightarrow 0$ ). Here $\tilde{\unicode[STIX]{x1D735}}$ is the spatial gradient in outer scaled coordinates: $\{\unicode[STIX]{x2202}/\unicode[STIX]{x2202}X,\unicode[STIX]{x2202}/\unicode[STIX]{x2202}Y,\unicode[STIX]{x2202}/\unicode[STIX]{x2202}Z\}$ . Since the particle is small with respect to the wall–particle gap ( $\unicode[STIX]{x1D705}/s\ll 1$ ), we retain only the zeroth- and first-order terms

(A 14) $$\begin{eqnarray}\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}_{2}|_{r=1}=\int _{0}^{\infty }\left[\begin{array}{@{}c@{}}\unicode[STIX]{x1D705}^{3}(-(b_{2}+b_{3})\unicode[STIX]{x1D706}^{2}/4)\{1,0,0\}\\ +\,\unicode[STIX]{x1D705}^{4}((b_{2}-b_{3})\unicode[STIX]{x1D706}^{3}/8)\{1,0,1\}\end{array}\right]\,\text{d}\unicode[STIX]{x1D706}+O(\unicode[STIX]{x1D705}^{5}).\end{eqnarray}$$

Substituting (3.4) and (3.6) in both (2.24) and (2.25) and using (A 13) and (A 14), we obtain

(A 15a,b ) $$\begin{eqnarray}\boldsymbol{F}_{M}=4\unicode[STIX]{x03C0}Ha\left(\frac{3\unicode[STIX]{x03C0}}{16}\unicode[STIX]{x1D705}^{4}(\mathfrak{Z}(4,s)-\mathfrak{Z}(4,1-s))\right)\boldsymbol{e}_{z}+O(\unicode[STIX]{x1D705}^{7})\quad \text{and}\quad \boldsymbol{L}_{M}=\mathbf{0}.\end{eqnarray}$$

The leading-order electrical force on the particle arises only due to the interaction of $O(1)$ source-dipole term ( $\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}_{1}$ ) and $O(\unicode[STIX]{x1D705}^{4})$ term in ( $\unicode[STIX]{x1D735}\unicode[STIX]{x1D713}_{2}$ ). This was also reported by Yariv (Reference Yariv2006) for the case of a particle remotely adjacent to a single wall (i.e. $\unicode[STIX]{x1D705}\ll s$ ).

A.4 Solution to $v_{3}^{(0)}$

Here, we provide the details of the evaluation of $\boldsymbol{v}_{3}^{(0)}$ (see § 3.3). The particle boundary condition in (3.13) requires us to calculate $\tilde{\boldsymbol{v}}_{2}^{(0)}$ in the vicinity of the particle. Since, $\tilde{\boldsymbol{v}}_{2}^{(0)}$ is represented in outer scaled coordinates, the particle surface is equivalent to $R\rightarrow 0$ . Upon expanding $\tilde{\boldsymbol{v}}_{2}^{(0)}$ about the origin, we obtain

(A 16) $$\begin{eqnarray}\boldsymbol{v}_{2}^{(0)}|_{r=1}=\int _{0}^{\infty }\!\left[\!\begin{array}{@{}c@{}}(2\ell _{4}+\ell _{5}+2\ell _{7}+\ell _{8})\unicode[STIX]{x1D706}/2-(2\ell _{4}+\ell _{5}-\ell _{6}-2\ell _{7}-\ell _{8}+\ell _{9})\unicode[STIX]{x1D706}^{2}\unicode[STIX]{x1D705}z/4\\ \quad +\,\unicode[STIX]{x1D705}^{3}HaZ_{w}\,\mathfrak{s}_{x}(\tilde{\unicode[STIX]{x1D713}}_{2})+\cdots \\ 0+\cdots \\ (-\ell _{4}-\ell _{5}-\ell _{6}+\ell _{7}+\ell _{8}+\ell _{9})\unicode[STIX]{x1D706}^{2}\unicode[STIX]{x1D705}x/4+\cdots \end{array}\right]\text{d}\unicode[STIX]{x1D703}_{C}.\end{eqnarray}$$

The derivation of $\tilde{\boldsymbol{v}}_{2}^{(0)}$ along with the evaluation $\ell _{4},\ell _{5},\ldots ,\ell _{9}$ are described in supplementary material. Having obtained the boundary condition for $\boldsymbol{v}_{3}^{(0)}$ at the particle surface, we use Lamb’s method to obtain the third reflection. The resulting solution has a form similar to (3.14) with coefficients $A_{3}$ , $B_{3}$ , $C_{3}$ and $D_{3}$ . These coefficients are in the integral form, owing to the integral form of (A 16). Since the force-free and torque-free arguments require only the coefficients of Stokeslet and rotlet field (Kim & Karrila Reference Kim and Karrila2013, p. 88), here we only report the coefficients $A_{3}$ and $C_{3}$ for brevity

(A 17) $$\begin{eqnarray}\left.\begin{array}{@{}c@{}}A_{3}={\textstyle \frac{-3}{4}}\displaystyle \int _{0}^{\infty }\left({\textstyle \frac{1}{2}}(2\ell _{4}+\ell _{5}+2\ell _{7}+\ell _{8})\unicode[STIX]{x1D706}+\unicode[STIX]{x1D705}^{3}Ha{Z_{w}}_{x}\mathfrak{s}_{x}(\tilde{\unicode[STIX]{x1D713}}_{2})\right)\,\text{d}\unicode[STIX]{x1D706}\\ C_{3}={\textstyle \frac{1}{4}}\displaystyle \int _{0}^{\infty }\left({\textstyle \frac{1}{2}}(\ell _{4}-2\ell _{6}-\ell _{7}+2\ell _{9})\unicode[STIX]{x1D706}^{2}\unicode[STIX]{x1D705}\right)\,\text{d}\unicode[STIX]{x1D706}.\end{array}\right\}\end{eqnarray}$$

Substitution of $\ell _{4},\ell _{5},\ldots ,\ell _{9}$ into the above equations results in (3.22)–(3.23).

A.5 Test field ( $\boldsymbol{u}^{t}$ )

Using the method of reflections we seek

(A 18a,b ) $$\begin{eqnarray}\boldsymbol{u}^{t}=\boldsymbol{u}_{1}^{t}+\boldsymbol{u}_{2}^{t}+\boldsymbol{u}_{3}^{t}+\cdots \,,\quad p^{t}=p_{1}^{t}+p_{2}^{t}+p_{3}^{t}+\cdots \,.\end{eqnarray}$$

Following Ho & Leal (Reference Ho and Leal1974), we obtain the first reflection $\boldsymbol{u}_{1}^{t}$

(A 19) $$\begin{eqnarray}\boldsymbol{u}_{1}^{t}=\frac{3}{4}\left(\boldsymbol{e}_{z}+\frac{z\boldsymbol{r}}{r^{2}}\right)\frac{1}{r}+\frac{1}{4}\left(\boldsymbol{e}_{z}-\frac{3z\boldsymbol{r}}{r^{2}}\right)\frac{1}{r^{3}}\end{eqnarray}$$

and the second reflection $\tilde{\boldsymbol{u}}_{1}^{t}=\{\tilde{u} _{1}^{t},\tilde{v}_{1}^{t},\tilde{w}_{1}^{t}\}$ ,

(A 20) $$\begin{eqnarray}\tilde{u} _{2}^{t}=\frac{1}{2\unicode[STIX]{x03C0}}\int _{-\infty }^{+\infty }\int _{-\infty }^{+\infty }\text{e}^{\text{i}\unicode[STIX]{x1D6E9}^{t}}\left(\text{e}^{(-\unicode[STIX]{x1D706}^{t}Z/2)}\left(\frac{h_{3}Z}{2}+\frac{h_{4}}{\unicode[STIX]{x1D706}^{t}}\right)+\text{e}^{(+\unicode[STIX]{x1D706}^{t}Z/2)}\left(\frac{h_{5}Z}{2}-\frac{h_{6}}{\unicode[STIX]{x1D706}^{t}}\right)\right)\text{i}\unicode[STIX]{x1D709}^{t}\,\text{d}\unicode[STIX]{x1D709}^{t}\,\text{d}\unicode[STIX]{x1D702}^{t},\end{eqnarray}$$
(A 21) $$\begin{eqnarray}\tilde{v}_{2}^{t}=\frac{1}{2\unicode[STIX]{x03C0}}\int _{-\infty }^{+\infty }\int _{-\infty }^{+\infty }\text{e}^{\text{i}\unicode[STIX]{x1D6E9}^{t}}\left(\text{e}^{(-\unicode[STIX]{x1D706}^{t}Z/2)}\left(\frac{h_{3}Z}{2}+\frac{h_{4}}{\unicode[STIX]{x1D706}^{t}}\right)+\text{e}^{(+\unicode[STIX]{x1D706}^{t}Z/2)}\left(\frac{h_{5}Z}{2}-\frac{h_{6}}{\unicode[STIX]{x1D706}^{t}}\right)\right)\text{i}\unicode[STIX]{x1D702}^{t}\,\text{d}\unicode[STIX]{x1D709}^{t}\,\text{d}\unicode[STIX]{x1D702}^{t},\end{eqnarray}$$
(A 22) $$\begin{eqnarray}\tilde{w}_{2}^{t}=\frac{1}{2\unicode[STIX]{x03C0}}\int _{-\infty }^{+\infty }\int _{-\infty }^{+\infty }\text{e}^{\text{i}\unicode[STIX]{x1D6E9}^{t}}\left(\begin{array}{@{}c@{}}-\text{e}^{(-\unicode[STIX]{x1D706}^{t}Z/2)}(h_{3}(1+\unicode[STIX]{x1D706}^{t}Z/2)+h_{4})\\ -\text{e}^{(+\unicode[STIX]{x1D706}^{t}Z/2)}(h_{5}(1-\unicode[STIX]{x1D706}^{t}Z/2)+h_{6})\end{array}\right)\text{d}\unicode[STIX]{x1D709}^{t}\,\text{d}\unicode[STIX]{x1D702}^{t}.\end{eqnarray}$$

Here, $\unicode[STIX]{x1D6E9}^{t}=(X\unicode[STIX]{x1D709}^{t}+Y\unicode[STIX]{x1D702}^{t})/2$ and $\unicode[STIX]{x1D706}^{t}=(\unicode[STIX]{x1D709}^{t\,^{2}}+\unicode[STIX]{x1D702}^{t\,^{2}})^{1/2}$ . The expressions for the terms $h_{3},h_{4},\ldots ,h_{6}$ are evaluated and are found to be identical to that reported by Ho & Leal (Reference Ho and Leal1974). The disturbance velocities can be reduced to single integral by the use of simple transformation techniques, which makes the evaluation inertial lift convenient. An interested reader can refer to the supplementary material.

Appendix B. Validation of $\boldsymbol{U}_{s}$ and $\unicode[STIX]{x1D734}_{s}$ with the literature

In the absence of electric fields, the expressions for $U_{s\,x}^{(0)}$ (3.24) and $\unicode[STIX]{x1D6FA}_{s\,y}^{(0)}$ (3.25) are identical to those obtained by Ho & Leal (Reference Ho and Leal1974).

For the pure electrokinetic flow (i.e. electrophoretic particle in electro-osmotic flow: $\unicode[STIX]{x1D6FC}=0,\hspace{2.22198pt}\unicode[STIX]{x1D6FD}=0,\hspace{2.22198pt}\text{and }\unicode[STIX]{x1D6FE}=0$ ), the dimensional electrophoretic translational velocity ( $\boldsymbol{U}_{s}^{\prime E}$ ) at the centreline ( $s=0.5$ ) is

(B 1) $$\begin{eqnarray}\frac{\boldsymbol{U}_{s}^{\prime E}}{E_{\infty }^{\prime }(\unicode[STIX]{x1D700}^{\prime }/4\unicode[STIX]{x03C0}\unicode[STIX]{x1D707}^{\prime })}=[(\unicode[STIX]{x1D701}_{p}^{\prime }-\unicode[STIX]{x1D701}_{w}^{\prime })-(0.259478\unicode[STIX]{x1D701}_{p}^{\prime }-0.262433\unicode[STIX]{x1D701}_{w}^{\prime })(a^{\prime }/d^{\prime })^{3}]\boldsymbol{e}_{x}.\end{eqnarray}$$

For a particle fixed at the centreline the expression derived by Keh & Anderson (Reference Keh and Anderson1985) in bounded electrokinetic flow is

(B 2) $$\begin{eqnarray}\frac{\boldsymbol{U}_{s}^{\prime E}}{E_{\infty }^{\prime }(\unicode[STIX]{x1D700}^{\prime }/4\unicode[STIX]{x03C0}\unicode[STIX]{x1D707}^{\prime })}=[1-0.267699(a^{\prime }/d^{\prime })^{3}+O(a^{\prime }/d^{\prime })^{5}](\unicode[STIX]{x1D701}_{p}^{\prime }-\unicode[STIX]{x1D701}_{w}^{\prime })\boldsymbol{e}_{x}.\end{eqnarray}$$

This difference arises as Keh & Anderson (Reference Keh and Anderson1985) used an alternative method of reflections whereas, we follow Brenner’s parallel method of reflections (see Luke (Reference Luke1989) for more details on the two methods). When the resistance due to Stokeslet ( $W_{A}$ ) is neglected in (3.24), for pure electrokinetic flow at $s=0.5$ , equation (B 2) is obtained. Since (3.24) – for pure electrokinetic flow – is valid for any arbitrary position between the walls, it is a generalization of results obtained by Keh & Anderson (Reference Keh and Anderson1985) up to $O(\unicode[STIX]{x1D705}^{3})$ .

Figure 10. Variation of the electrophoretic rotational velocity with respect to wall separation for $a=10~\unicode[STIX]{x03BC}\text{m}$ .

For the pure electrokinetic flow, the weak particle rotation ( $\unicode[STIX]{x1D734}_{s}^{E}\sim O(\unicode[STIX]{x1D705}^{4})$ ) near the walls is negative as depicted by figure 10. This is interestingly opposite to that observed in Couette, Poiseuille flow and sedimentation flows. Near the wall, the potential distribution around the particle exerts a hydrodynamic torque (through slip at the particle surface, see (3.16)) in the negative $y$ -direction, and is sufficiently strong to overcome torque generated due to wall-induced viscous resistance (Keh & Chen Reference Keh and Chen1988). We compare the rotational velocity expressed in (3.25) with that obtained exactly by Keh & Chen (Reference Keh and Chen1988) (in the presence of a single wall) and find a good agreement (see figure 10).

Figure 11. (a) Cylinder circumscribing the spherical particle of radius $\unicode[STIX]{x1D705}$ , (b) front 2-D projection showing the splitting of polar angle into four identical sections. The integral is evaluated in the blank space. Here, $r_{out}$ is the outer limit of radius.

Appendix C.

In this appendix, we analytically find the contribution from the sub-region which extends from the spherical surface to the circumscribing cylinder (see § 4.3). The spherical coordinate system is employed to find the volume integral as shown in figure 11(a). The azimuthal angle $\unicode[STIX]{x1D719}_{s}$ spans from 0 to $2\unicode[STIX]{x03C0}$ . The polar angle $\unicode[STIX]{x1D713}_{s}$ (spanning from 0 to $\unicode[STIX]{x03C0}$ ) is divided into four sections. This splitting results in four right angled triangles and allows us to exploit trigonometric identities to specify limits in the radial direction $(\int _{\unicode[STIX]{x1D705}}^{r_{out}}\,\text{d}r)$ . For instance, in the section-I (0 to $\unicode[STIX]{x03C0}/4$ ), we obtain the following relation using trigonometry: $\cos \unicode[STIX]{x1D713}_{s}=\unicode[STIX]{x1D705}/r_{out}$ . Therefore, the radius of integration spans from $\unicode[STIX]{x1D705}\rightarrow \unicode[STIX]{x1D705}\sec \unicode[STIX]{x1D713}_{s}$ . Extending the procedure to all the four sections, transforms the volume integral as

(C 1) $$\begin{eqnarray}\unicode[STIX]{x1D716}=\int _{0}^{2\unicode[STIX]{x03C0}}\left(\!\begin{array}{@{}c@{}}\left(\displaystyle \int _{0}^{\unicode[STIX]{x03C0}/4}\displaystyle \int _{\unicode[STIX]{x1D705}}^{\unicode[STIX]{x1D705}\sec \unicode[STIX]{x1D713}_{s}}{\mathcal{H}}(r^{2}\sin \unicode[STIX]{x1D713}_{s})\,\text{d}r\,\text{d}\unicode[STIX]{x1D713}_{s}\right)\\ +\left(\displaystyle \int _{\unicode[STIX]{x03C0}/4}^{\unicode[STIX]{x03C0}/2}\displaystyle \int _{\unicode[STIX]{x1D705}}^{\unicode[STIX]{x1D705}\csc \unicode[STIX]{x1D713}_{s}}{\mathcal{H}}(r^{2}\sin \unicode[STIX]{x1D713}_{s})\,\text{d}r\,\text{d}\unicode[STIX]{x1D713}_{s}\right)\\ +\left(\displaystyle \int _{\unicode[STIX]{x03C0}/2}^{3\unicode[STIX]{x03C0}/4}\displaystyle \int _{\unicode[STIX]{x1D705}}^{\unicode[STIX]{x1D705}\csc \unicode[STIX]{x1D713}_{s}}{\mathcal{H}}(r^{2}\sin \unicode[STIX]{x1D713}_{s})\,\text{d}r\,\text{d}\unicode[STIX]{x1D713}_{s}\right)\\ +\left(\displaystyle \int _{3\unicode[STIX]{x03C0}/4}^{\unicode[STIX]{x03C0}}\displaystyle \int _{\unicode[STIX]{x1D705}}^{-\unicode[STIX]{x1D705}\sec \unicode[STIX]{x1D713}_{s}}{\mathcal{H}}(r^{2}\sin \unicode[STIX]{x1D713}_{s})\,\text{d}r\,\text{d}\unicode[STIX]{x1D713}_{s}\right)\end{array}\!\right)\text{d}\unicode[STIX]{x1D719}_{s}.\end{eqnarray}$$

Here, ${\mathcal{H}}$ is the integrand in spherical coordinates. The contribution from the four sections is found to be

(C 2) $$\begin{eqnarray}\unicode[STIX]{x1D716}=-Re_{p}\unicode[STIX]{x1D6FD}(1.7HaZ_{p}+1.603\unicode[STIX]{x1D705}+O(\unicode[STIX]{x1D705}^{2})),\end{eqnarray}$$

and is accounted in the results discussed in § 7. For the case of neutrally and non-neutrally buoyant (inert) particle, we find that the contribution from this sub-region is negligible.

References

Abramowitz, M. & Stegen, I. 1972 Handbook of Mathematical Functions: With Formulas, Graphs, and Mathematical Tables, vol. 55. Dover.Google Scholar
Anderson, J. L. 1989 Colloid transport by interfacial forces. Annu. Rev. Fluid Mech. 21 (1), 6199.10.1146/annurev.fl.21.010189.000425Google Scholar
Becker, L. E., McKinley, G. H. & Stone, H. A. 1996 Sedimentation of a sphere near a plane wall: weak non-Newtonian and inertial effects. J. Non-Newtonian Fluid Mech. 63 (2–3), 201233.10.1016/0377-0257(95)01424-1Google Scholar
Bike, S. G. & Prieve, D. C. 1995 Electrokinetic lift of a sphere moving in slow shear flow parallel to a wall: (ii). Theory. J. Colloid Interface Sci. 175 (2), 422434.10.1006/jcis.1995.1472Google Scholar
Brenner, H. 1962 Effect of finite boundaries on the Stokes resistance of an arbitrary particle. J. Fluid Mech. 12 (1), 3548.10.1017/S0022112062000026Google Scholar
Bretherton, F. P. 1962 The motion of rigid particles in a shear flow at low Reynolds number. J. Fluid Mech. 14 (2), 284304.10.1017/S002211206200124XGoogle Scholar
Cevheri, N. & Yoda, M. 2014 Electrokinetically driven reversible banding of colloidal particles near the wall. Lab on a Chip 14 (8), 13911394.10.1039/c3lc51341fGoogle Scholar
Cox, R. G. & Brenner, H. 1968 The lateral migration of solid particles in Poiseuille flow. I. Theory. Chem. Engng Sci. 23 (2), 147173.10.1016/0009-2509(68)87059-9Google Scholar
Faxén, H. 1922 The resistance to the movement of a rigid sphere in a zippered liquid enclosed between two parallel plane w. Ann. Phys. 373 (10), 89119.10.1002/andp.19223731003Google Scholar
Feng, J., Hu, H. H. & Joseph, D. D. 1994 Direct simulation of initial value problems for the motion of solid bodies in a Newtonian fluid. Part 2. Couette and Poiseuille flows. J. Fluid Mech. 277, 271301.10.1017/S0022112094002764Google Scholar
Guazzelli, E. & Morris, J. F. 2011 A Physical Introduction to Suspension Dynamics, vol. 45. Cambridge University Press.10.1017/CBO9780511894671Google Scholar
Happel, J. & Brenner, H. 2012 Low Reynolds Number Hydrodynamics: With Special Applications to Particulate Media, vol. 1. Springer Science & Business Media.Google Scholar
Ho, B. P. & Leal, L. G. 1974 Inertial migration of rigid spheres in two-dimensional unidirectional flows. J. Fluid Mech. 65 (2), 365400.10.1017/S0022112074001431Google Scholar
Hood, K., Lee, S. & Roper, M. 2015 Inertial migration of a rigid sphere in three-dimensional Poiseuille flow. J. Fluid Mech. 765, 452479.10.1017/jfm.2014.739Google Scholar
Keh, H.-J. & Anderson, J. L. 1985 Boundary effects on electrophoretic motion of colloidal spheres. J. Fluid Mech. 153, 417439.10.1017/S002211208500132XGoogle Scholar
Keh, H. J. & Chen, S. B. 1988 Electrophoresis of a colloidal sphere parallel to a dielectric plane. J. Fluid Mech. 194, 377390.10.1017/S0022112088003039Google Scholar
Kim, S. & Karrila, S. J. 2013 Microhydrodynamics: Principles and Selected Applications. Courier Corporation.Google Scholar
Kim, Y. W. & Yoo, J. Y. 2009a Axisymmetric flow focusing of particles in a single microchannel. Lab on a Chip 9 (8), 10431045.10.1039/b815286aGoogle Scholar
Kim, Y. W. & Yoo, J. Y. 2009b Three-dimensional focusing of red blood cells in microchannel flows for bio-sensing applications. Biosens. Bioelectr. 24 (12), 36773682.10.1016/j.bios.2009.05.037Google Scholar
Kirby, B. J. 2010 Micro- and Nanoscale Fluid Mechanics: Transport in Microfluidic Devices. Cambridge University Press.10.1017/CBO9780511760723Google Scholar
Lamb, H. 1975 Hydrodynamics, 6th edn. Cambridge University Press.Google Scholar
Lee, D., Nam, S. M., Kim, J.-a., Di Carlo, D. & Lee, W. 2018 Active control of inertial focusing positions and particle separations enabled by velocity profile tuning with coflow systems. Anal. Chem. 90 (4), 29022911.10.1021/acs.analchem.7b05143Google Scholar
Li, D. & Xuan, X. 2018 Electrophoretic slip-tuned particle migration in microchannel viscoelastic fluid flows. Phys. Rev. Fluids 3 (7), 074202.10.1103/PhysRevFluids.3.074202Google Scholar
Luke, J. H. 1989 Convergence of a multiple reflection method for calculating Stokes flow in a suspension. SIAM J. Appl. Maths 49 (6), 16351651.10.1137/0149099Google Scholar
Martel, J. M. & Toner, M. 2014 Inertial focusing in microfluidics. Annu. Rev. Biomed. Engng 16, 371396.10.1146/annurev-bioeng-121813-120704Google Scholar
Matas, J. P., Morris, J. F. & Guazzelli, E. 2004 Lateral forces on a sphere. Oil Gas Sci. Technol. 59 (1), 5970.10.2516/ogst:2004006Google Scholar
O’Brien, R. W. & Hunter, R. J. 1981 The electrophoretic mobility of large colloidal particles. Can. J. Chem. 59 (13), 18781887.10.1139/v81-280Google Scholar
O’Brien, R. W. & White, L. R. 1978 Electrophoretic mobility of a spherical colloidal particle. J. Chem. Soc. Faraday Trans. 74, 16071626.10.1039/f29787401607Google Scholar
Rossi, M., Marin, A., Cevheri, N., Kähler, C. J. & Yoda, M. 2019 Particle distribution and velocity in electrokinetically induced banding. Microfluid. Nanofluid. 23 (5), 67.10.1007/s10404-019-2227-9Google Scholar
Rubinow, S. I. & Keller, J. B. 1961 The transverse force on a spinning sphere moving in a viscous fluid. J. Fluid Mech. 11 (3), 447459.10.1017/S0022112061000640Google Scholar
Saffman, P. G. T. 1965 The lift on a small sphere in a slow shear flow. J. Fluid Mech. 22 (2), 385400.10.1017/S0022112065000824Google Scholar
Schnitzer, O., Frankel, I. & Yariv, E. 2012a Streaming-potential phenomena in the thin-debye-layer limit. Part 2. Moderate Péclet numbers. J. Fluid Mech. 704, 109136.10.1017/jfm.2012.221Google Scholar
Schnitzer, O., Frankel, I. & Yariv, E. 2012b Streaming-potential phenomena in the thin-debye-layer limit. Part 2. Moderate Péclet numbers. J. Fluid Mech. 704, 109136.10.1017/jfm.2012.221Google Scholar
Schnitzer, O. & Yariv, E. 2012 Macroscale description of electrokinetic flows at large zeta potentials: nonlinear surface conduction. Phys. Rev. E 86 (2), 021503.Google Scholar
Schnitzer, O. & Yariv, E. 2016 Streaming-potential phenomena in the thin-debye-layer limit. Part 3. Shear-induced electroviscous repulsion. J. Fluid Mech. 786, 84109.10.1017/jfm.2015.647Google Scholar
Segre, G. & Silberberg, A. 1961 Radial particle displacements in Poiseuille flow of suspensions. Nature 189 (4760), 209210.10.1038/189209a0Google Scholar
Segre, G. & Silberberg, A. J. 1962a Behaviour of macroscopic rigid spheres in Poiseuille flow. Part. 1. Determination of local concentration by statistical analysis of particle passages through crossed light beams. J. Fluid Mech. 14 (1), 115135.10.1017/S002211206200110XGoogle Scholar
Segre, G. & Silberberg, A. J. 1962b Behaviour of macroscopic rigid spheres in Poiseuille flow. Part. 2. Experimental results and interpretation. J. Fluid Mech. 14 (1), 136157.10.1017/S0022112062001111Google Scholar
Smoluchowski, M. 1903 Contribution à la théorie de l’endosmose électrique et de quelques phénomènes corrélatifs. Bull. Akad. Sci. Cracovie. 8, 182200.Google Scholar
Strogatz, S. H. 2018 Nonlinear Dynamics and Chaos: With Applications to Physics, Biology, Chemistry, and Engineering. CRC Press.10.1201/9780429492563Google Scholar
Vasseur, P. & Cox, R. G. 1976 The lateral migration of a spherical particle in two-dimensional shear flows. J. Fluid Mech. 78 (2), 385413.10.1017/S0022112076002498Google Scholar
Yariv, E. 2006 ‘Force-free’ electrophoresis? Phys. Fluids 18 (3), 031702.10.1063/1.2185690Google Scholar
Yariv, E. 2016 Dielectrophoretic sphere–wall repulsion due to a uniform electric field. Soft Matter 12 (29), 62776284.10.1039/C6SM00462HGoogle Scholar
Yee, A. & Yoda, M. 2018 Experimental observations of bands of suspended colloidal particles subject to shear flow and steady electric field. Microfluid. Nanofluid. 22 (10), 113.10.1007/s10404-018-2136-3Google Scholar
Yuan, D., Pan, C., Zhang, J., Yan, S., Zhao, Q., Alici, G. & Li, W. 2016 Tunable particle focusing in a straight channel with symmetric semicircle obstacle arrays using electrophoresis-modified inertial effects. Micromachines 7 (11), 195.10.3390/mi7110195Google Scholar
Zhang, J., Yan, S., Yuan, D., Alici, G., Nguyen, N.-T., Warkiani, M. E. & Li, W. 2016 Fundamentals and applications of inertial microfluidics: a review. Lab on a Chip 16 (1), 1034.10.1039/C5LC01159KGoogle Scholar
Figure 0

Figure 1. Disturbance velocity fields around the particle in a quiescent fluid for movements due to (a) forced (sedimentation) and (b) force-free (phoresis) mechanisms. The external field is applied in the horizontal direction.

Figure 1

Table 1. A summary of theoretical studies in the past addressing various forces acting on the particle. The table is divided with respect to origin of the lift: (i) weak inertia and (ii) electrostatics and electrokinetics. $Re$ is the flow Reynolds number; $Re_{p}$ is the particle Reynolds number based on average shear; $Re_{V}$ is the particle Reynolds number based on particle velocity relative to background flow; $Pe$ is the Péclet number defined as $a^{\prime 2}G^{\prime }/D_{i}^{\prime }$ ($G^{\prime }$ is the background velocity gradient and $D_{i}^{\prime }$ being the ionic diffusion coefficient of $i$th ionic species); $\unicode[STIX]{x1D716}$ is the particle–wall gap, non-dimensionalized with respect to particle radius $a^{\prime }$.

Figure 2

Figure 2. Schematic depicting the problem configuration and the coordinate system in particle reference frame. The dashed layer around the particle and walls depicts the outer edge of the double layer. Prime denotes the dimensional variables and $\unicode[STIX]{x1D703}$ denotes the polar angle measured from the $z^{\prime }$-axis; $a^{\prime }$ includes the particle radius and thin electrical double layer $\unicode[STIX]{x1D706}_{d}^{\prime }$.

Figure 3

Figure 3. Comparison with the previous theoretical studies (Ho & Leal 1974; Vasseur & Cox 1976) for the inertial lift force experienced by a particle, as a function of distance from the bottom wall for: (a) Couette flow and (b) Poiseuille flow.

Figure 4

Figure 4. Variation of leading constituents of inertial lift force as a function of distance from the bottom wall for Poiseuille flow. Here, stresslet-wall force (SWF) is the ‘wall lift force’ and stresslet-curvature force (SCF) is the ‘shear-gradient lift force’.

Figure 5

Figure 5. Variation of the inertial lift force on the electrophoretic particle with distance from the bottom wall: (a) effect of zeta potential for $Ha=1.25$ ($E_{\infty }^{\prime }=70~\text{V}~\text{cm}^{-1}$); (b) comparison of the phoretic lift with SCF (stresslet-curvature force) and SWF (stresslet-wall force) for $Z_{p}=0.67$. The dashed line shows the analytical expression, expressed in (4.7) (which does not account for the wall effects). Parameters: $\unicode[STIX]{x1D701}_{p}^{\prime }=47~\text{mV}$, $U_{max}^{\prime }=2.25~\text{mm}~\text{s}^{-1}$, $a^{\prime }=10~\unicode[STIX]{x03BC}\text{m}$, $l^{\prime }=1~\text{mm}$, $\unicode[STIX]{x1D700}^{\prime }=80\unicode[STIX]{x1D700}_{0}^{\prime }$, $\unicode[STIX]{x1D707}^{\prime }=10^{-3}~\text{Pa}~\text{s}$.

Figure 6

Table 2. Components which constitute the electrophoresis combined inertial lift force. The forces arising due to electrophoresis are subscripted by ‘E’ because the external agency is electric field. The first two components are the same as described in figure 4.

Figure 7

Figure 6. Variation of (a) major and (b) minor components of the phoretic lift, for a leading particle. See table 2 for the details of abbreviations. Parameters: $\unicode[STIX]{x1D701}_{p}^{\prime }=47~\text{mV}$, $U_{max}^{\prime }=2.25~\text{mm}~\text{s}^{-1}$, $a^{\prime }=10~\unicode[STIX]{x03BC}\text{m}$, $l^{\prime }=1~\text{mm}$, $\unicode[STIX]{x1D700}^{\prime }=80\unicode[STIX]{x1D700}_{0}^{\prime }$, $\unicode[STIX]{x1D707}^{\prime }=10^{-3}~\text{Pa}~\text{s}$, $E_{\infty }^{\prime }=70~\text{V}~\text{cm}^{-1}$.

Figure 8

Figure 7. Lift force on a non-neutrally buoyant particle in a Poiseuille flow and comparison with Vasseur & Cox (1976). Parameters: $a^{\prime }=10~\unicode[STIX]{x03BC}\text{m}$, $l^{\prime }=1~\text{mm}$, $U_{max}^{\prime }=2.25~\text{mm}~\text{s}^{-1}$, $\unicode[STIX]{x1D707}^{\prime }=10^{-3}~\text{Pa}~\text{s}$ and $\unicode[STIX]{x0394}\unicode[STIX]{x1D70C}^{\prime }=100~\text{kg}~\text{m}^{-3}$.

Figure 9

Table 3. Lift force components which comprise the additional lift force occurring due to a non-neutrally buoyant particle. The subscript ‘G’ denotes that the forces arise from an external gravitational field.

Figure 10

Figure 8. Variation of (a) major components (SSF$_{\text{G}}$ and SCF$_{\text{G}}$) and (b) minor components (SWF$_{\text{G}}$ and SLF$_{\text{G}}$) of buoyancy combined inertial force as a function of distance from the bottom wall (see table 3). Parameters: $a^{\prime }=10~\unicode[STIX]{x03BC}\text{m}$, $l^{\prime }=1~\text{mm}$, $U_{max}^{\prime }=2.25~\text{mm}~\text{s}^{-1}$, $\unicode[STIX]{x1D707}^{\prime }=10^{-3}~\text{Pa}~\text{s}$ and $\unicode[STIX]{x0394}\unicode[STIX]{x1D70C}^{\prime }=100~\text{kg}~\text{m}^{-3}$.

Figure 11

Figure 9. (a) Comparison of electrophoresis combined inertial lift (EIL) with the electric lift (EL) (3.8) for $\unicode[STIX]{x1D701}_{p}^{\prime }=47~\text{mV}$ and $\unicode[STIX]{x1D701}_{p}^{\prime }=-47~\text{mV}$. Parameters: $Ha=+1.25$; $E_{\infty }^{\prime }=70~\text{V}~\text{cm}^{-1}$, $U_{max}^{\prime }=2.25~\text{mm}~\text{s}^{-1}$, $a^{\prime }=10~\unicode[STIX]{x03BC}\text{m}$, $l^{\prime }=1~\text{mm}$, $\unicode[STIX]{x1D700}^{\prime }=80\unicode[STIX]{x1D700}_{0}^{\prime }$, $\unicode[STIX]{x1D707}^{\prime }=10^{-3}~\text{Pa}~\text{s}$, $\unicode[STIX]{x1D70C}^{\prime }=10^{3}~\text{kg}~\text{m}^{-3}$. (b) Effect of $Ha$ and size ratio ($\unicode[STIX]{x1D705}=0.01$ and $\unicode[STIX]{x1D705}=0.02$) on the equilibrium positions ($\unicode[STIX]{x1D701}_{p}^{\prime }=47~\text{mV}$). A negative $Ha$ implies that the electric field and the flow are in the opposite directions.

Figure 12

Figure 10. Variation of the electrophoretic rotational velocity with respect to wall separation for $a=10~\unicode[STIX]{x03BC}\text{m}$.

Figure 13

Figure 11. (a) Cylinder circumscribing the spherical particle of radius $\unicode[STIX]{x1D705}$, (b) front 2-D projection showing the splitting of polar angle into four identical sections. The integral is evaluated in the blank space. Here, $r_{out}$ is the outer limit of radius.

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