Passive microwave measurements of Arctic sea ice have been conducted over the last 50 years from space and during airborne, ship- and ground-based measurement campaigns. The different radiometric signatures of distinct surface types have led to satellite retrievals of, e.g., sea-ice concentration. In contrast, ground-based upward-viewing radiometers measure radiation emitted from the atmosphere and are used to retrieve atmospheric variables. Here, we present results from a ship-based radiometer setup with a mirror construction, which allows us to switch between atmospheric and surface measurements flexibly. This way, in summer 2022, surface observations in the Arctic marginal sea-ice zone could be performed from the research vessel Polarstern by two radiometers covering the frequency range from 22 to 243 GHz. At low frequencies, the brightness temperatures show clear signatures of different surface conditions. We estimate emissivities at 53∘ zenith angle from infrared-based skin temperatures. Predominantly vertically polarized 22–31 GHz emissivities are between 0.51 and 0.55 for open ocean and around 0.95 for sea ice. Predominantly horizontally polarized 243 GHz ocean emissivities are around 0.78 and ice surfaces exhibit a large variability from 0.67 to 0.82. Our results can improve the characterization of surface emissions in satellite retrieval algorithms.