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The Synthesis of Boron-Containing Ceramics by Pyrolysis of Polymeric Lewis Base Adducts of Decaborane(14)

Published online by Cambridge University Press:  25 February 2011

Dietmar Seyferth  and
William Smith Rees Jr
Dietmar Seyferth
Affiliation:
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139
William Smith Rees Jr
Affiliation:
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139
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Abstract

Polymeric adducts, [B10H12L∼∼L]x, have been prepared by reaction of B10H14 with diphosphines and diamines. These show good promise as precursors whose pyrolysis can give either boron carbide (in the case of the diphosphine polymers) or boron carbonitride and boron nitride (in the case of the diamine polymers).

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 121: Symposium H – Better Ceramics Through Chemistry III , 1988 , 449
Copyright
Copyright © Materials Research Society 1988

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References

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