Hostname: page-component-6dbcb7884d-wnk8j Total loading time: 0 Render date: 2025-02-13T22:01:29.163Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and Characterization of Novel Platinum Acetylide Oligomers

Published online by Cambridge University Press:  15 February 2011

Thomas M. Cooper ,
Benjamin C. Hall ,
Daniel G. McLean ,
Joy E. Rogers ,
Aaron R. Burke ,
Kenneth Turnbull  and
Andrew Weisner
Thomas M. Cooper
Affiliation:
Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright-Patterson Air Force Base, OH, 45433;
Benjamin C. Hall
Affiliation:
Systran, Inc, Dayton, OH, 45431;
Daniel G. McLean
Affiliation:
Science Applications International Corporation, Dayton, OH, 45433;
Joy E. Rogers
Affiliation:
UES, Inc. Dayton, OH, 45432;
Aaron R. Burke
Affiliation:
Anteon Corporation, Dayton, OH, 45431;
Kenneth Turnbull
Affiliation:
Dept. of Chemistry, Wright State University, Dayton, OH, 45435
Andrew Weisner
Affiliation:
Dept. of Chemistry, Wright State University, Dayton, OH, 45435
Get access

Abstract

As part of an effort to develop a spectroscopic structure-property relationship in platinum acetylide oligomers, we have prepared a series of bidentate Pt(PBu3)2L2 compounds. The ligand was the series o-syd-C6H4-CΞC-(C6H4-CΞC)n-H, n = 0,1,2. The terminal oligomer unit consisted of a sydnone group ortho to the acetylene carbon. The compounds were characterized by various methods, including 13C-NMR, ground state absorption, fluorescence, phosphorescence and laser flash photolysis. The acetylenic 13C-NMR resonances showed sydnone influences that decreased with increasing number of monomer units. The ground state absorption spectra were slightly red shifted from those of the baseline oligomers not having a sydnone group. The low temperature emission and excitation spectra showed complex dependence on excitation and emission wavelengths, suggesting the chromphores resided in a distribution of solvent environments and conformations. Finally, broad triplet state absorption spectra were observed, with absorption throughout the visible and near infrared regions.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 771: Symposium L – Organic and Polymeric Materials and Devices , 2003 , L4.21
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Cooper, T.M., McLean, D. G., and Rogers, J. E., Chem. Phys. Lett. 349, 31 (2001).Google Scholar
2. Rogers, J. E., Cooper, T. M., Fleitz, P.A., Glass, D. J., and McLean, D. G., J. Phys. Chem. A 106, 10108 (2002).Google Scholar
3. Bhattacharyya, K., Muneer, M., Tikarl, R. K., Das, P. K., and George, M. V., Journal of the Indian Chemical Society 63, 43 (1986).Google Scholar
4. Nespurek, S., Lukas, J., Boehm, S., and Bastl, Z., Journal of Photochemistry and Photobiology, A: Chemistry 84, 257 (1994).Google Scholar
5. Morley, J. O., Journal of Physical Chemistry 99, 1923 (1995).Google Scholar
6. McKay, T. J., Bolger, J. A., Staromlynska, J., and Davy, J. R., J. Chem. Phys. 108, 5537 (1998).Google Scholar
7. Liu, Y., Jiang, S., Glusac, K. D., Powell, D. H., Anderson, D. F., and Schanze, K. S., J. Amer. Chem. Soc. 124, 12412 (2002).Google Scholar
8. Friebolin, H., Basic One- and Two- dimensional NMR spectroscopy (VCH Publishers, 1991).Google Scholar
9. Fan, J. M., Wang, Y., and Ueng, C. H., Journal of Physical Chemistry 97, 8193 (1993).Google Scholar
10. Cooper, T. M., in Encyclopedia of Nanomaterials and Nanotechnology, edited by Nalwa, H. S. (American Scientific Publishers, 2003).Google Scholar
11. Sacksteder, L., Baralt, E., DeGraff, B. A., Lukehart, C. M., and Demas, J. N., Inorg. Chem. 30, 2468 (1991).Google Scholar
12. Sigman, M. E. and Closs, G. L., J. Phys. Chem 95, 5012 (1991).Google Scholar
13. Beljonne, D., Wittman, H. F., Kohler, A., G. S., Younus, M., Lewis, J., Raithby, P. R., Khan, M. S., Friend, R. H., and Bredas, J. L., J. Chem. Phys. 105, 3868 (1996).Google Scholar
14. Hutchison, C.A. Jr andKemple, M. D., J. Chem. Phys. 74, 6505 (1979).Google Scholar