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Quantitative evaluation of bundling effect on single walled carbon nanotubes by resonance Raman spectra

Published online by Cambridge University Press:  01 February 2011

Zhengtang Luo ,
Rongfu Li ,
Sang Nyon Kim  and
Fotios Papadimitrakopoulos
Zhengtang Luo
Affiliation:
Nanomaterials Optoelectronics Laboratory, Department of Chemistry, Polymer Program, Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269–3136
Rongfu Li
Affiliation:
Nanomaterials Optoelectronics Laboratory, Department of Chemistry, Polymer Program, Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269–3136
Sang Nyon Kim
Affiliation:
Nanomaterials Optoelectronics Laboratory, Department of Chemistry, Polymer Program, Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269–3136
Fotios Papadimitrakopoulos*
Affiliation:
Nanomaterials Optoelectronics Laboratory, Department of Chemistry, Polymer Program, Institute of Materials Science, University of Connecticut, Storrs, Connecticut 06269–3136
*
email: papadim@mail.ims.uconn.edu
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Abstract

The radial breathing mode (RBM) region of the resonance Raman spectra of HiPco single walled carbon nanotubes (SWNTs) was investigated as a function of aggregation. This was modeled using an energetic deviation term (ΔE), imparted to the optical transitions (Eii(n, m)) by bundling effect. Eii(n, m) values obtained from photoluminescence (PL) measurements were used to reconstruct these RBM profiles. The simulation revealed that the PL-determined Eii(n, m) set provided a good fit in terms of peak position. Providing an accurate set of Eii(n, m) values becomes available, the RBM profile reconstruction methodology discussed herein could greatly enhance our ability to model a range of physicochemical changes to the immediate environment of SWNTs.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 858: Symposium HH – Functional Carbon Nanotubes , 2004 , HH13.14
Copyright
Copyright © Materials Research Society 2005

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