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Is the Rigid-Band Model Applicable in Lithium Intercalation Compounds?

Published online by Cambridge University Press:  25 February 2011

C. Julien  and
M. Balkanski
C. Julien
Affiliation:
Laboratoire de Physique des Solides, associé auCNRS Université Pierre et Marie Curie, 4 place Jussieu, 75252 Paris Cédex 05, France
M. Balkanski
Affiliation:
Laboratoire de Physique des Solides, associé auCNRS Université Pierre et Marie Curie, 4 place Jussieu, 75252 Paris Cédex 05, France
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Abstract

Numerous layered compounds are interesting materials in which lithium intercalation occurs primarily without destruction of the host lattice. In many cases a rigid-band model is a useful first approximation for describing the changes in electronic properties of the host material with intercalation. This paper presents some recent experimental results obtained on transition-metal chalcogenide compounds and on transition-metal oxides as well. We shall observe, nevertheless, that the rigid-band model is not applicable to all of the intercalated materials. The applicability of the rigid-band model may be used as a test for the most desirable properties of a good intercalation material. This needs to be more extensively documented for their possible applications as insertion electrodes in solid state batteries.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 293: Symposium U – Solid State Ionics III , 1992 , 27
Copyright
Copyright © Materials Research Society 1993

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