Published online by Cambridge University Press: 15 February 2011
Non-stoichiometric films are particularly attractive for non-volatile memory applications. In this work low-pressure chemical vapor deposition (LPCVD) using silane and nitrous oxide gases were used to deposit thin silicon-rich SiO2 films. Reliability issues concerning these nonstoichiometric oxides have been studied in comparison to ultrathin conventional thermal oxides. It has been found that with an increase in the silicon content, the current injection efficiency at a given electric field increases. This has significant advantage in terms of low programming voltage applications. There is also a considerable reduction in electron trapping, extremely large increase in charge-to-breakdown and negligible interface state generation in comparison to ultrathin thermal oxides. These characteristics of non-stoichiometric oxide films can be explained by a modified conduction mechanism which in turn is due to dispersed crystallites in the oxide film.