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Conjugated Polymers Containing Pendant Terpyridine Complexes as Photoactive Sensors

Published online by Cambridge University Press:  10 February 2011

Biwang Jiang ,
Shailesh Sahay  and
Wayne E. Jones Jr.
Biwang Jiang
Affiliation:
Department of Chemistry and Institute for Materials Research, State University of New York at Binghamton, Binghamton, NY 13902
Shailesh Sahay
Affiliation:
Department of Chemistry and Institute for Materials Research, State University of New York at Binghamton, Binghamton, NY 13902
Wayne E. Jones Jr.
Affiliation:
Department of Chemistry and Institute for Materials Research, State University of New York at Binghamton, Binghamton, NY 13902
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Abstract

We have synthesized a novel conjugated polymer containing terpyridine receptors. This conjugated, polymer-based fluorescent chemosensory system exhibits unusually high sensitivity toward transition metal ions (∼-10−9 M). The fluorescence quenching response of the terpyridine containing conjugated polymer to transition metal ions is related to a facile energy migration in which energy from absorption of a photon, can migrate through the conjugated polymer system and be quenched by trapping sites. Terpyridine receptors can readily bind to transition metal ions and create a low lying Metal to Ligand Charge Transfer (MLCT) state which can act as an excitation trap.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 488: Symposium J – Electrical, Optical & Magnetic Properties of Organic IV , 1997 , 671
Copyright
Copyright © Materials Research Society 1998

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