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Effects of Redox Conditions of Water on Pu and Cm Leaching from Waste Glass

Published online by Cambridge University Press:  03 September 2012

Y. Inagaki ,
A. Sakai ,
H. Furuya ,
K. Idemitsu ,
T. Arima ,
T. Banba ,
T. Maeda ,
S. Matsumoto  and
Y. Tamura
Y. Inagaki
Affiliation:
Dept. of Nucl. Eng., Kyushu Univ., Fukuoka 812, JAPAN.
A. Sakai
Affiliation:
Dept. of Nucl. Eng., Kyushu Univ., Fukuoka 812, JAPAN.
H. Furuya
Affiliation:
Dept. of Nucl. Eng., Kyushu Univ., Fukuoka 812, JAPAN.
K. Idemitsu
Affiliation:
Dept. of Nucl. Eng., Kyushu Univ., Fukuoka 812, JAPAN.
T. Arima
Affiliation:
Dept. of Nucl. Eng., Kyushu Univ., Fukuoka 812, JAPAN.
T. Banba
Affiliation:
Dept. of Environ. Safe. Research, Japan Atomic Energy Research Institute, Tokai-mura, Ibaraki 319–11, JAPAN.
T. Maeda
Affiliation:
Dept. of Environ. Safe. Research, Japan Atomic Energy Research Institute, Tokai-mura, Ibaraki 319–11, JAPAN.
S. Matsumoto
Affiliation:
Dept. of Environ. Safe. Research, Japan Atomic Energy Research Institute, Tokai-mura, Ibaraki 319–11, JAPAN.
Y. Tamura
Affiliation:
Dept. of Environ. Safe. Research, Japan Atomic Energy Research Institute, Tokai-mura, Ibaraki 319–11, JAPAN.
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Abstract

Static corrosion tests were performed on the simulated waste glass doped with Pu and Cm (PuO2; 0.22wt%, Cm2O3; 0.09%) in deionized water at 90 °C with S/V ratio of 2600 m−1 under oxidizing and reducing conditions, respectively. The corrosion tests under oxidizing conditions were performed in air, while the corrosion tests under reducing conditions were performed in an airtight stainless steel container purged with mixed gas (Ar+5%H2), where the Eh of the solution was maintained at approximately -0.45 V vs SHE. The results showed that the redox conditions have no remarkable influence on the leaching behavior of Pu and Cm. It was also observed that the Pu and Cm concentrations in the 1.8nm filtered solutions were one or two orders of magnitude lower than those in the 450nm filtered solutions under both redox conditions, which suggests that the insoluble suspended fractions (colloidal particles) with the size from 1.8nm to 450nm are dominant phase for Pu and Cm in the solution under both redox conditions.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 465: Symposium II – Scienfific Basis for Nuclear Waste Management XX , 1996 , 213
Copyright
Copyright © Materials Research Society 1997

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References

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