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Cathodoluminescence microcharacterization of point defects in α-quartz

Published online by Cambridge University Press:  05 July 2018

M. A. Stevens-Kalceff
M. A. Stevens-Kalceff*
Affiliation:
School of Physics and Electron Microscope Unit, University of New South Wales, Sydney NSW 2052, Australia
*
* E-mail: Marion.Stevens-Kalceff@unsw.edu.au
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Abstract

Cathodoluminescence (CL) spectroscopy in an SEM has been used to investigate the point defect structure of clear natural α-quartz at 295 K. Cathodoluminescence processes and experimental factors that influence the CL spectra from α-quartz are investigated. Electron irradiation may induce changes in the average local crystal micro structure of quartz, locally transforming it to a less dense, amorphized state. The observed CL emissions are identified with a range of native and impurity defect centres including: interstitial molecular O at 0.968 eV; a charge-compensated substitutional Fe3+ impurity centre at —1.65 eV; a non-bridging oxygen hole centre (NBOHC) at 1.9 eV; an NBOHC with OH~ precursor at 1.95 eV; an NBOHC with a non-bridging impurity (e.g. Li+, Na+ or K+) precursor at — 1.9 eV; a radiative recombination of the self-trapped exciton (STE) associated with an E' centre in electron-irradiation-amorphized quartz at 2.3 eV; a radiative recombination of the STE associated with the E1' centre in α-quartz at 2.7 eV; a charge-compensated-substitutional Al3+ impurity centre at 3.3 eV; and a neutral relaxed O vacancy at 4.3 eV. In addition, unresolved contributions from O-deficient defects in electron-irradiation-amorphized SiO2 are likely at —2.7 and 4.3 eV.

Keywords

quartzsilicon dioxidecathodoluminescencespectroscopySEM.
Type
Research Article
Information
Mineralogical Magazine , Volume 73 , Issue 4 , August 2009 , pp. 585 - 605
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2009

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