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The potential of near-infrared reflectance spectroscopy to analyse soil chemical and physical characteristics

Published online by Cambridge University Press:  17 April 2003

D. COZZOLINO
Affiliation:
Soil Department, Instituto Nacional de Investigacion Agropecuaria, INIA La Estanzuela, Ruta 50-km 12, Colonia-Uruguay, CC 39173 Present address: The Australian Wine Research Institute, Waite Road, P.O. Box 197, Urrbrae, SA 5064, South Australia. Email: Daniel.Cozzolino@awri.com.au
A. MORÓN
Affiliation:
Soil Department, Instituto Nacional de Investigacion Agropecuaria, INIA La Estanzuela, Ruta 50-km 12, Colonia-Uruguay, CC 39173
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Abstract

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Near-infrared reflectance spectroscopy (NIRS) was used for the analysis of soil samples for silt, sand, clay, calcium (Ca), potassium (K), sodium (Na), magnesium (Mg), copper (Cu) and iron (Fe). A total of 332 samples of different soils from Uruguay (South America) were used. The samples were scanned in a NIRS 6500 (NIRSystems, Silver Spring, MD, USA) in reflectance. Cross validation was applied to avoid overfitting of the models. The coefficient of determination in calibration (R^2_{\rm cal}) and the standard errors in cross validation (SECV) were 0·80 (SECV: 6·8), 0·84 (SECV: 6·0), 0·90 (SECV: 3·6) in per cent for sand, silt and clay respectively. For both macro and microelements the R^2_{\rm cal} and SECV were 0·80 (SECV: 0·1), 0·95 (SECV: 2·9), 0·90 (SECV 0·8), for K, Ca, Mg in g/kg respectively, and 0·86 (SECV: 0·82) and 0·92 (SECV: 25·5) for Cu and Fe in mg/kg. It was concluded that NIRS has a great potential as an analytical method for soil routine analysis due to the speed and low cost of analysis.

Type
Research Article
Copyright
© 2003 Cambridge University Press