The Devonian, Pivot Coal Measures in southern Victoria Land are non-carbonaceous. The sequence contains bedding parallel, titaniferous ironstones up to 50 cm thick, but no coal or carbonaceous shale, the unit is consequently renamed Pivot Member of the Arena Sandstone. The more Fe-Ti oxide-rich (up to 40 modal %) beds appear black and coal-like with conchoidal fracture and closely spaced cleat-like fractures. The coal-like beds grade laterally and vertically into less altered sedimentary rocks in which fine bedding-parallel concentrations of Fe-Ti oxide pick-out parting surfaces on ripples and other sedimentary structures. Thin section petrography shows that the Fe-Ti oxide is replacive, and outcrop relationships show that the replacement was related to dolerite intrusion 200 million years after the sedimentary host was deposited. Replacement of muscovite, biotite and chlorite by Fe-Ti-oxide occurred at 179 ± 3 Ma, at pressures of 0.3–0.4 kbar and at temperatures as low as 380°C.