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What Can Crystallography Tell us About the Intermediate Range Order in Borate Glasses?

Published online by Cambridge University Press:  06 March 2019

Adrian C. Wright ,
Natalia M. Vedishcheva  and
Boris A. Shakhmatkin
Adrian C. Wright
Affiliation:
J.J. Thomson Physical Laboratory, University of Reading, Whiteknights, Reading, Berkshire, RG6 6AF, United Kingdom.
Natalia M. Vedishcheva
Affiliation:
Institute of Silicate Chemistry of the Russian Academy of Sciences, Ul. Odoevskogo, 24, Korp. 2, Sankt Petersburg, 199155, Russia.
Boris A. Shakhmatkin
Affiliation:
Institute of Silicate Chemistry of the Russian Academy of Sciences, Ul. Odoevskogo, 24, Korp. 2, Sankt Petersburg, 199155, Russia.
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Abstract

Crystallographic data for a wide range of crystalline borates are used as a basis to propose a set of topological criteria for the formation of vitreous borate networks, taking into account the topological degrees of freedom necessary for conventional glass formation. It is shown that considerable insight into the structural criteria for the formation of borate networks can be gained by studying the arrangements of superstructural units found in the various crystalline borates.

Type
Research Article
Information
Advances in X-Ray Analysis , Volume 39: Forty-Fourth Annual Conference on Applications of X-ray Analysis, July 31 - August 4, 1995 , 1995 , pp. 535 - 552
Copyright
Copyright © International Centre for Diffraction Data 1995

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